Security feature, printing ink, document of value, and manufacturing method
AssigneeGiesecke+Devrient Currency Technology GmbH
InventorsAnika Stritt, Verena Engelhardt
Life of this patent
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Abstract
A security feature for safeguarding a document of value, includes an organometallic luminescent substance which, on excitation with radiation in the UV-A range, has emission of radiation in the visible wavelength range, especially with green and/or red light, wherein the luminescent substance is based on a polynuclear, heteroleptic lanthanoid complex of the formula (I) [Mx(NN ligand)a(OO ligand)b] (I) where x, a and b are natural numbers, where x≥2, a≥2 and b≥6; M is a lanthanoid selected from the group consisting of Eu and Th; the OO ligand is a ligand that coordinates via oxygen atoms and the NN ligand is a nitrogen ligand having a phenanthroline base skeleton.
Claims24
A security feature for safeguarding a document of value, comprising an organometallic luminescent substance which, on excitation with radiation in a UV-A range, has emission of radiation in a visible wavelength range,
- wherein the luminescent substance is based on a polynuclear heteroleptic lanthanoid complex of the formula (I)
- [Mx(NN ligand)a(OO ligand)b] (I)
- where
- x, a and b are natural numbers, where x≥2, a≥2 and b≥6;
- M is a lanthanoid selected from the group consisting of Eu and Tb;
- the OO ligand is a ligand of the formula (II) that coordinates via oxygen atoms:
- where
- R1 to R5 are the same or different and are independently selected from the group consisting of hydrogen atom, OH, OCH3 and halogen atom;
- the NN ligand is a nitrogen ligand with a phenanthroline base skeleton of the general formula (III) or of the general formula (IV)
- where
- Y is NR9 or Y is an oxygen atom;
- R6 and R7 are the same or different and are independently selected from the group consisting of hydrogen atom and an electron-donating group;
- R8 and R9 are the same or different and are independently selected from the group consisting of hydrogen atom, substituted or unsubstituted alkyl radical having 1 to 8 carbon atoms, substituted or unsubstituted aryl radical, substituted or unsubstituted piperidine radical and substituted or unsubstituted benzyl radical.
Dependencies are inferred from the claim text.