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US 12,538,924 B2Granted
Pesticidally active heterocyclic derivatives with sulfur containing substituents
AssigneeSyngenta Crop Protection AG
InventorsVikas Sikervar, Indira Sen, Daniel Emery, Michel Muehlebach, Sebastian Rendler, André Stoller, Anke Buchholz
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Abstract
Compounds of the Formula(I) wherein the substituents are as defined in claim 1. Furthermore, the present invention relates to agrochemical compositions which comprise compounds of formula (I), to preparation of these compositions, and to the use of the compounds or compositions 10 in agriculture or horticulture for combating, preventing or controlling animal pests, including arthropods and in particular insects, moluscs, nematodes or representatives of the order Acarina.
Claims22
A compound of formula (I)
- wherein
- G1 and G2 are, independently from each other, CH or N;
- R2 is C1-C4haloalkyl, C1-C4haloalkylsulfanyl, C1-C4haloalkylsulfinyl, C1-C4haloalkylsulfonyl or C1-C6haloalkoxy, C1-C4haloalkylsulfonyloxy;
- Q is a radical selected from the group consisting of formula Qa and Qb
- wherein the arrow denotes the point of attachment to the nitrogen atom of the bicyclic ring;
- and wherein A represents CH or N;
- X is S, SO, or SO2;
- R1 is C1-C4alkyl, or C3-C6cycloalkyl-C1-C4alkyl;
- Q1 is hydrogen, halogen, C1-C6haloalkyl, C3-C6cycloalkyl, C3-C6cycloalkyl monosubstituted by cyano, C1-C6cyanoalkyl, C1-C6cyanoalkoxy, C1-C6haloalkoxy, —N(R4)2, —N(R4)C(═O)R5, —N(R4)CON(R4)2, (oxazolidin-2-one)-3-yl, or 2-pyridyloxy;
- or
- Q1 is a five- to six-membered aromatic ring system, linked via a ring carbon atom to the ring which contains the substituent A, said ring system is unsubstitued or is mono- or polysubstituted by substituents selected from the group consisting of halogen, cyano, C1-C4alkyl, C1-C4haloalkyl, C1-C4alkoxy, C1-C4haloalkoxy, C1-C4alkylsulfanyl, C1-C4alkylsulfinyl and C1-C4alkylsulfonyl;
- and said ring system can contain 1, 2 or 3 ring heteroatoms selected from the group consisting of nitrogen, oxygen and sulfur, where said ring system may not contain more than one ring oxygen atom and not more than one ring sulfur atom;
- or
- Q1 is a five-membered aromatic ring system linked via a ring nitrogen atom to the ring which contains the substituent A, said ring system is unsubstituted or is mono- or polysubstituted by substituents selected from the group consisting of halogen, cyano, C1-C4alkyl, C1-C4haloalkyl, C1-C4alkoxy, C1-C4haloalkoxy, C1-C4alkylsulfanyl, C1-C4alkylsulfinyl and C1-C4alkylsulfonyl;
- and said ring system contains 1, 2 or 3 ring heteroatoms selected from the group consisting of nitrogen, oxygen and sulfur, where said ring system contains at least one ring nitrogen atom and may not contain more than one ring oxygen atom and not more than one ring sulfur atom;
- R3 is hydrogen, halogen or C-C4alkyl;
- each R4 independently is hydrogen, C1-C4alkyl or C3-C6cycloalkyl;
- and
- R5 is C1-C6alkyl, C1-C6haloalkyl or C3-C6cycloalkyl;
- or
- an agrochemically acceptable salt, stereoisomer, enantiomer, tautomer or N-oxide of a compound of formula I.
18 more elements
A compound of formula XVII-a
- wherein
- G1 and G2 are, independently from each other, CH or N;
- R2 is C1-C6haloalkyl, C1-C4haloalkylsulfanyl, C1-C4haloalkylsulfinyl, C1-C4haloalkylsulfonyl or C1-C6haloalkoxy, C1-C4haloalkylsulfonyloxy;
- Q is a radical selected from the group consisting of formula Qa and Qb
- wherein the arrow denotes the point of attachment to the nitrogen atom of the bicyclic ring;
- and wherein A represents CH or N;
- X is S, SO, or SO2;
- R1 is C1-C4alkyl, or C3-C6cycloalkyl-C1-C4alkyl;
- Q1 is hydrogen, halogen, C1-C6haloalkyl, C3-C6cycloalkyl, C3-C6cycloalkyl monosubstituted by cyano, C1-C6cyanoalkyl, C1-C6cyanoalkoxy, C1-C6haloalkoxy, —N(R4)2, —N(R4)C(═O)R5, —N(R4)CON(R4)2, (oxazolidin-2-one)-3-yl, or 2-pyridyloxy;
- or
- Q1 is a five- to six-membered aromatic ring system, linked via a ring carbon atom to the ring which contains the substituent A, said ring system is unsubstitued or is mono- or polysubstituted by substituents selected from the group consisting of halogen, cyano, C1-C4alkyl, C1-C4haloalkyl, C1-C4alkoxy, C1-C4haloalkoxy, C1-C4alkylsulfanyl, C1-C4alkylsulfinyl and C1-C4alkylsulfonyl;
- and said ring system can contain 1, 2 or 3 ring heteroatoms selected from the group consisting of nitrogen, oxygen and sulfur, where said ring system may not contain more than one ring oxygen atom and not more than one ring sulfur atom;
- or
- Q1 is a five-membered aromatic ring system linked via a ring nitrogen atom to the ring which contains the substituent A, said ring system is unsubstituted or is mono- or polysubstituted by substituents selected from the group consisting of halogen, cyano, C1-C4alkyl, C1-C4haloalkyl, C1-C4alkoxy, C1-C4haloalkoxy, C1-C4alkylsulfanyl, C1-C4alkylsulfinyl and C1-C4alkylsulfonyl;
- and said ring system contains 1, 2 or 3 ring heteroatoms selected from the group consisting of nitrogen, oxygen and sulfur, where said ring system contains at least one ring nitrogen atom and may not contain more than one ring oxygen atom and not more than one ring sulfur atom;
- R3 is hydrogen, halogen or C1-C4alkyl;
- each R4 independently is hydrogen, C1-C4alkyl or C3-C6cycloalkyl;
- and
- R5 is C1-C6alkyl, C1-C6haloalkyl or C3-C6cycloalkyl;
- and
- Ra is hydrogen, C1-C6alkyl, benzyl or phenyl.
18 more elements
A compound of formula IX-a
- wherein
- R1 is C1-C4alkyl, or C3-C6cycloalkyl-C1-C4alkyl;
- X is S, SO, or SO2;
- and
- Q1a is 1-cyanocyclopropyl, 1-cyano-1-methyl-ethyl or 2-pyridyloxy.
2 more elements
Dependencies are inferred from the claim text.