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US 12,534,602 B2Granted
Polyethylene homopolymer compositions with balanced properties
AssigneeNOVA Chemicals (International) S.A.
InventorsPatrick Lam, Monika Kleczek, Eric Vignola
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Abstract
A polyethylene homopolymer composition having a weight average molecular weight Mw, of from 75,000 to 95,000; an Mz of from 200,000 to 325,000; a molecular weight distribution Mw/Mn of from 6 to 12 and a melt index, I2 of from 1.5 to 2.8 grams per 10 minutes can be used to prepare films having a good balance of optical properties and resistance to moisture transmission.
Claims15
A polyethylene composition comprising at least two ethylene homopolymer blend components, wherein said composition has:
- (i) a density of from 0.96 to 0.97 g/cc;
- (ii) an Mw of from 75,000 to 95,000;
- (iii) an Mn of from 7000 to 12,000;
- (iv) an Mz of from 200,000 to 325,000;
- (v) a molecular weight distribution, Mw/Mn of from 6 to 12;
- (vii) a melt index, I2, as determined by ASTM D1238 at 190° C., using a 2.16 kilogram load, of from 1.5 to 2.8 grams per 10 minutes;
- and further characterized in that
- (viii) from 25 to 55 weight % of said composition has a molecular weight of less than or equal to 20,000;
- wherein said composition comprises a first blend component containing 45 to 60 weight % of said composition and a second blend component containing from 55 to 40 weight % of said composition, wherein said first blend component has:
- A1) an Mw/Mn of from 1.8 to 2.5;
- and
- A2) a melt index, I2, as determined by ASTM D1238 at 190° C., using a 2.16 kilogram load, of from 3,000 to 25,000 grams per 10 minutes;
- and
- wherein said second blend component has:
- B1) an Mw/Mn of from 1.8 to 2.5;
- and
- B2) a melt index, I2, as determined by ASTM D1238 at 190° C., using a 2.16 kilogram load, of from 0.05 to 0.5 grams per 10 minutes;
- and
- wherein the first and second blend components are polymers that are the product of a polymerization process in which only ethylene is deliberately present as a polymerizable monomer.
16 more elements
Dependencies are inferred from the claim text.