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US 12,534,544 B2Granted
Solid titanium catalyst component, olefin polymerization catalyst, olefin polymerization method, and propylene polymer
AssigneeMitsui Chemicals, Inc.
InventorsTakashi Kimura, Makoto Isogai, Yasushi Nakayama, Kenji Michiue, Takashi Jinnai, Wataru Yamada, Shotaro Takano, Hiroshi Terao, Takaaki Yano, Yoshiyuki Totani, Sunil Krzysztof Moorthi, Takashi Nakano
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Abstract
The solid titanium catalyst component (I) of the present invention contains titanium, magnesium, halogen, and a cyclic multiple-ester-group-containing compound (a) represented by the following formula (1).
Claims13
A solid titanium catalyst component (I) comprising titanium, magnesium, halogen, and a cyclic multiple-ester-group-containing compound (a) represented by the following formula (1):
- wherein n1 to n4 are each independently an integer of 0 to 2, m is 0 or 1, and x is an integer of 0 to 10, with a relationship of m+x≥1 being satisfied;
- R1 and R2 are each independently a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms;
- R3 to R16 and R are each independently a hydrogen atom, a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, or a halogen atom;
- a hydrogen atom, a carbon atom, or both, of R1 to R16 and R are optionally replaced by at least one atom selected from the group consisting of a nitrogen atom, an oxygen atom, a phosphorus atom, a halogen atom, and a silicon atom;
- and two or more selected from R3 to R16 and R are optionally bonded to one another to form a monocyclic or polycyclic ring, and adjacent substituents are optionally directly bonded to form a multiple bond;
- Ca, Cb, and Cc are carbon atoms, and in a carbon-carbon bond of a cyclic structure formed of Ca, Cb, and Cc, R bonded to adjacent carbon are optionally directly bonded to one another to form a multiple bond;
- and
- A is a single bond or a divalent linking group having a chain with a length of 1 to 3 atoms between two free radicals,
- wherein any two or more of R3-R10 may be absent on adjacent carbon atoms, and a bond between adjacent carbon atoms where two or more of R3-R10 are absent may comprise a double carbon-carbon bond or a triple carbon-carbon bond;
- and
- wherein R may be absent on any two or more of adjacent carbon atoms, and a bond between adjacent carbon atoms where R is absent may comprise a double carbon-carbon bond or a triple carbon-carbon bond.
8 more elements
Dependencies are inferred from the claim text.