Aliphatic polyester copolymer
AssigneesMitsubishi Gas Chemical Company, Inc., The University of Tokyo
InventorsAkira Maehara, Tadahisa Iwata, Taizo Kabe, Yuki Kawamura
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Abstract
An object of the present invention is to provide a stretchable polyester having shape followability and flexibility by elastic response and being able to suppress deterioration over time due to secondary crystallization. The present invention provides a stretchable polyester which is an aliphatic copolymer polyester containing two or more types of monomer units, wherein the stretchable polyester contains an α-form and an amorphous structure, and a degree of orientation determined by X-ray of the α-form is 50% or greater.
Claims18
A stretchable polyester, consisting of:
- an aliphatic copolymer polyester consisting of, in polymerized form, a 3-hydroxybutyrate unit and a 4-hydroxybutyrate unit,
- wherein the stretchable polyester is produced by crystallizing aliphatic copolymer polyester;
- stretching the crystallized aliphatic copolymer polyester by subjecting the crystallized aliphatic copolymer polyester to an orientation treatment;
- and removing a tensile load which was added by the orientation and stretching of the crystallized aliphatic copolymer polyester,
- wherein the stretchable polyester has an α-form and an amorphous structure,
- wherein the α-form has a degree of orientation of 50% or greater as determined by X-ray,
- wherein the stretchable polyester, in a stretched state, has a β-form detectable by wide-angle X-ray diffraction and small-angle X-ray scattering,
- wherein the stretchable polyester, in an unloaded state, has the β-form reduced compared to the stretched state, or not detectable, by wide-angle X-ray diffraction and small-angle X-ray scattering,
- wherein the stretchable polyester has an elasticity with a tensile elongation recovery rate in a range of from 20 to 100%, and
- wherein the 4-hydroxybutyrate unit is present in the aliphatic copolymer polyester in a range of from 10 to 30 mol %, with respect to all monomer units.
Dependencies are inferred from the claim text.