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US 12,532,414 B2Granted
Liquid crystal polymer film, polymer film, and laminate
AssigneeFUJIFILM Corporation
InventorYasuyuki Sasada
Life of this patent
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Abstract
Provided are a liquid crystal polymer film or a polymer film, which has low linear expansion coefficient and has excellent adhesiveness with a metal layer. The liquid crystal polymer film includes a layer A and a layer B on at least one surface of the layer A, in which the layer A contains a liquid crystal polymer and a linear expansion coefficient of the liquid crystal polymer film is −20 ppm/K to 50 ppm/K.
Claims15
A liquid crystal polymer film comprising:
- a layer A;
- a layer B on at least one surface of the layer A;
- and
- a layer C, wherein the layer B, the layer A, and the layer C are provided in this order, the liquid crystal polymer film contains a filler in at least one layer of the layer A or the layer B, and a number density of the filler is higher inside the liquid crystal polymer film than on a surface of the liquid crystal polymer film,
- wherein the layer A contains a liquid crystal polymer, a linear expansion coefficient of the liquid crystal polymer film is −20 ppm/K to 50 ppm/K, and
- the liquid crystal polymer has a constitutional unit represented by any of Formulae (2) and (3),
- —CO—Ar2—CO— Formula (2)
- —X—Ar3—Y— Formula (3)
- in Formulae (2) and (3), Ar2 and Ar3 each independently represent a group represented by Formula (4), X and Y each independently represent an oxygen atom or an imino group, and hydrogen atoms in Ar2 and Ar3 may be each independently substituted with a halogen atom, an alkyl group, or an aryl group
- —Ar4—Z—Ar5— Formula (4)
- in Formula (4), Ar4 and Ar5 each independently represent a phenylene group or a naphthylene group, and at least one of Ar4 and Ar5 represents a naphthylene group, and Z represents an oxygen atom, a sulfur atom, a carbonyl group, a sulfonyl group, or an alkylene group.
8 more elements
Dependencies are inferred from the claim text.