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US 12,529,014 B2Granted
Polyurethane redeposition inhibiting polymers and detergent compositions containing same
AssigneeLubrizol Advanced Materials, Inc.
InventorsSteven M. Raders, Yunpeng Zhu, Nima Hakim, Janean Nagorski
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Abstract
The present technology relates to polymeric additives and their incorporation into cleaning compositions useful in household detergents and other related uses including, dishwash (institutional and consumer), hard surface cleaners and textile care. The disclosed cleaning compositions include a detersive agent and a soil redeposition inhibiting agent. In one aspect, the soil redeposition inhibiting agent is selected from a functionalized polyurethane polymer.
Claims41
A detergent composition comprising:
- a) from about 1 to about 99 wt % of at least one surfactant;
- and
- b) a polyurethane anti-redeposition polymer comprising from about 35 to 90 wt. % of a poly(C2-C4 alkylene oxide) based on the total weight of the polyurethane polymer, wherein not less than at least 5 wt. % of the poly(C2-C4 alkylene oxide) is poly(ethylene oxide), and wherein at least 5 wt. % of the poly(C2-C4 alkylene oxide) based on the total weight of the polyurethane polymer is incorporated in lateral chains pending from the polyurethane polymer, wherein said polyurethane polymer is prepared by reacting together:
- (i) one or more polyisocyanates having an average functionality of from about 2 to about 2.5;
- (ii) one or more compounds having at least one poly(C2-C4 alkylene oxide) chain and at least two groups which react with isocyanate groups and are located at one end of said compound such that the poly(C2-C4 alkylene oxide) chain is laterally disposed relative to the polyurethane polymer backbone;
- (iii) one or more compounds containing at least one acid group and at least two groups which react with isocyanate groups;
- (iv) optionally, one or more chain extending compounds having a number average molecular weight of from about 32 to about 3000 g/mole containing at least two groups which react with isocyanate groups;
- and
- (v) optionally, one or more chain terminator compounds containing one group which reacts with isocyanate groups;
- wherein the polyurethane has an acid value ranging from about 1 to about 300 mg of KOH/g;
- and wherein said detergent composition is a form selected from the group consisting of a granular detergent, a liquid laundry detergent, a gel detergent, a unit dose detergent, a detergent contained in water soluble pouch, a liquid hand dishwashing detergent, a laundry pre-treat product, an automatic dish washing detergent, and a hard surface cleaner.
8 more elements
Dependencies are inferred from the claim text.