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US 12,528,891 B2Granted
Hybrid supported metallocene catalyst and method for preparing polypropylene using the same
AssigneeLG Chem, Ltd.
InventorsByung Seok Kim, Seyoung Kim, Minyoung Kang, Insun Lee, Seok Hwan Kim, Donghyeon Gwon, Yoonchul Jung
Life of this patent
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Abstract
Disclosed is a hybrid supported metallocene catalyst exhibiting high activity in propylene polymerization and useful for preparing a polypropylene having high melt strength by introducing long chain branches into the polypropylene molecule, and to a method for preparing a polypropylene using the same.
Claims15
A hybrid supported metallocene catalyst, comprising at least one first metallocene compound selected from a compound represented by Chemical Formula 1;
- at least one second metallocene compound selected from a compound represented by Chemical Formula 2;
- and a support on which the first and the second metallocene compounds are supported,
- wherein a molar ratio of the first metallocene compound and the second metallocene compound is 4:1 to 1:1:
- wherein in Chemical Formula 1,
- M is a Group 4 transition metal,
- X1 and X2 are each independently hydrogen;
- halogen;
- or C1-20 alkyl;
- A is carbon or silicon,
- R11 and R12 are each independently hydrogen;
- halogen;
- C1-20 alkyl;
- C2-20 alkoxyalkyl;
- or C6-20 aryl;
- R21 is methyl,
- R22 is C3-20 alkyl;
- C3-20 alkoxyalkyl;
- or C3-20 alkenyl,
- R23 is unsubstituted C6-20 aryl;
- or C7-20 alkylaryl,
- R24 and R25 are each hydrogen;
- or R24 and R25 are connected with each other to form a C3-10 cycloalkane ring,
- R26 is C1-20 alkyl, and
- R27 is unsubstituted C6-20 aryl;
- or C7-20 alkylaryl,
- wherein in Chemical Formula 2,
- M′is a Group 4 transition metal,
- X′1 and X′2 are each independently halogen,
- A′ is carbon or silicon,
- R′11 and R′12 are each independently C1-20 alkyl;
- C6-20 aryl;
- or C2-20 alkoxyalkyl,
- R′21 and R′23 are each independently C1-20 alkyl, and
- R′22 and R′24 are each independently C6-30 alkylaryl;
- or C6-30 aryl.
32 more elements
Dependencies are inferred from the claim text.