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US 12,528,072 B2Granted
Method for preparing super absorbent polymer
AssigneeLG Chem, Ltd.
InventorsSung Soo Park, Heechang Woo, Gicheul Kim
Life of this patent
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Abstract
The present disclosure relates to a method for preparing a super absorbent polymer. More specifically, it relates to a method for preparing a super absorbent polymer capable of improving drying efficiency, reducing a generation amount of re-fines, and simultaneously improving absorption performance, in particular, absorption under pressure and permeability of the finally prepared super absorbent polymer by controlling granulation strength of the extruded fine reassembly.
Claims12
A method for preparing a super absorbent polymer, comprising:
- preparing a hydrogel polymer by polymerizing a monomer composition comprising a water-soluble ethylene-based unsaturated monomer having at least partially neutralized acidic groups and a polymerization initiator;
- drying and pulverizing the hydrogel polymer, and performing classification into fines having a particle diameter of less than 150 μm and normal particles having a particle diameter of 150 to 850 μm;
- preparing a fine reassembly by mixing the fines with water and a polycarboxylic acid-based copolymer, followed by reassembling;
- preparing an extruded fine reassembly by extruding the fine reassembly while adding water, followed by drying, pulverization and classification;
- and
- mixing the extruded fine reassembly with the normal particles, and then performing a surface cross-linking reaction by adding a surface cross-linking agent;
- wherein 30 to 80 parts by weight of water are used based on 100 parts by weight of the fines in the preparation of the fine reassembly, and
- 15 to 30 parts by weight of water are used based on the fine reassembly in the preparation of the extruded fine reassembly,
- wherein the polycarboxylic acid-based copolymer is a copolymer comprising at least one of a repeating unit represented by the following Chemical Formula 1-a or a repeating unit represented by the following Chemical Formula 1-b:
- wherein, in Chemical Formulae 1-a and 1-b,
- R1, R2 and R3 are each independently hydrogen or a C1 to C6 alkyl group,
- RO is a C2 to C4 oxyalkylene group,
- M1 is hydrogen, or a monovalent metal or non-metal ion,
- X is —COO—, a C1 to C5 alkyloxy group, or a C1 to C5 alkyldioxy group,
- m is an integer of 1 to 100,
- n is an integer of 1 to 1000, and
- p is an integer of 1 to 150, and when p is 2 or more, two or more repeating —RO— are the same as or different from each other.
14 more elements
Dependencies are inferred from the claim text.