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US 12,523,932 B2Granted
Resist composition and pattern forming process
AssigneeShin-Etsu Chemical Co., Ltd.
InventorsJun Hatakeyama, Masaki Ohashi
Life of this patent
Estimating the term…
Abstract
A resist composition comprising a sulfonium salt of a carboxylic acid having a nitro-substituted benzene ring is provided. The carboxylic acid is free of iodine and bromine, and when the benzene ring is fluorinated, the number of fluorine atoms is up to 3. The resist composition offers a high sensitivity, reduced LWR and improved CDU independent of whether it is of positive or negative tone.
Claims15
A resist composition comprising a sulfonium salt of a carboxylic acid having a benzene ring substituted with at least one nitro group, wherein the carboxylic acid is free of iodine and bromine,
- wherein the sulfonium salt has the formula (A):
- wherein R1 is each independently chlorine, hydroxy group, amino group, or a C1-C20 hydrocarbyl group, C1-C20 hydrocarbyloxy group, C2-C20 hydrocarbylcarbonyloxy group, C2-C20 hydrocarbyloxycarbonyl group, C2-C20 hydrocarbyloxycarbonyloxy group, or C1-C20 hydrocarbylsulfonyl group, which may contain chlorine, hydroxy, amino, ether bond or ester bond, or —N(R1A)(R1B), —N(R1C)—C(═O)—R1D, —N(R1C)—C(═O)—O—R1D, or —N(R1E)—S(═O)2—R1F, R1A and R1B are each independently hydrogen or a C1-C6 saturated hydrocarbyl group, R1C and RIE are each independently hydrogen or a C1-C6 saturated hydrocarbyl group which may contain halogen, hydroxy moiety, C1-C6 saturated hydrocarbyloxy moiety, C2-C6 saturated hydrocarbylcarbonyl moiety or C2-C6 saturated hydrocarbylcarbonyloxy moiety, R1D and R1F are each independently a C1-C16 aliphatic hydrocarbyl group, C6-C14 aryl group or C7-C15 aralkyl group, which may contain halogen, hydroxy moiety, C1-C6 saturated hydrocarbyloxy moiety, C2-C6 saturated hydrocarbylcarbonyl moiety or C2-C6 saturated hydrocarbylcarbonyloxy moiety,
- R2 is fluorine,
- R3 to R5 are each independently halogen or a C1-C20 hydrocarbyl group which may contain a heteroatom, R3 and R4 may bond together to form a ring with the sulfur atom to which they are attached,
- X is a single bond or a C1-C20 divalent linking group which may contain an ether bond, carbonyl moiety, ester bond, amide bond, sultone ring, lactam ring, carbonate bond, halogen, hydroxy moiety or carboxy moiety,
- m is an integer of 1 to 3, n1 is an integer of 0 to 3, n2 is 0, and 1≤m+n1+n2≤5.
3 more elements
Dependencies are inferred from the claim text.