System and method for efficient carbon dioxide capture

A system for the efficient collection of carbon dioxide, comprising:

• a recovery subsystem, comprising:
• a heat pump in thermal communication with a condenser and a vaporizer, the condenser in fluidic communication with a reservoir;
• a liquid pump in fluid communication with the reservoir and the vaporizer, the liquid pump configured to pump condensate to the vaporizer from the reservoir, revaporizing the condensate to form a water vapor;
• and
• a vacuum compressor in fluid communication with a product outlet providing a product stream and also in fluidic communication with the reservoir;
• a plurality of sorbent vessels having at least six sorbent vessels, each sorbent vessel comprising a spray nozzle and a sorbent structure having a moisture-swing sorbent material, the spray nozzle coupled to a liquid water supply, each sorbent vessel being in fluidic communication with the vacuum compressor, the condenser, and the vaporizer of the recovery subsystem and with at least a subset of the plurality of sorbent vessels, the fluidic communication of each sorbent vessel being controlled through a plurality of valves, each sorbent vessel of the plurality of sorbent vessels configured to transition between a gas collection phase, a gas recovery phase, and a heat recovery phase, with the plurality of sorbent vessels comprising the gas collection phase, the gas recovery phase, and the heat recovery phase simultaneously;
• wherein the gas collection phase comprises the sorbent material of the sorbent vessel being in fluidic communication with the atmosphere, absorbing carbon dioxide;
• wherein the gas recovery phase has N gas recovery stages, each sorbent vessel configured to transition through each of the N gas recovery stages sequentially, the sorbent vessel releasing a product gas mixture and receiving water vapor causing captured carbon dioxide to desorb from the sorbent material, the first (N−1) gas recovery stages comprising the sorbent vessel being in fluidic communication with the recovery subsystem at a downstream pressure and a different sorbent vessel in the heat recovery phase at an upstream pressure, the Nth gas recovery stage comprising the sorbent vessel being in fluidic communication with the condenser at the downstream pressure and the vaporizer at the upstream pressure, the upstream pressure being greater than the downstream pressure for each gas recovery stage, the upstream pressure of each gas recovery stage being greater than the upstream pressure of the previous gas recovery stage, the water vapor having the upstream pressure being a carrier gas forcing liquid water from the liquid water supply out of the spray nozzle, creating a spray of liquid water droplets to cause the carbon dioxide to desorb from the sorbent material;
• wherein the heat recovery phase has (N−1) heat recovery stages, each heat recovery stage comprising the sorbent vessel being in fluidic communication with a different sorbent vessel in the gas recovery phase at a heating pressure, the heating pressure decreasing in each subsequent heat recovery stage, the sorbent vessel configured to transition through each of the (N−1) heat recovery stages sequentially.

A method for the efficient collection of carbon dioxide, comprising:

• placing a plurality of sorbent vessels in fluidic communication with a recovery subsystem of the system, the sorbent vessels belonging to a system and each comprising a sorbent structure having a sorbent material, the recovery subsystem comprising:
• a heat pump in thermal communication with a condenser and a vaporizer, the condenser in fluidic communication with a reservoir;
• a liquid pump in fluid communication with the reservoir and the vaporizer, the liquid pump configured to pump condensate to the vaporizer from the reservoir, revaporizing the condensate to form a water vapor;
• and
• a vacuum compressor in fluid communication with a product outlet providing a product stream and also in fluidic communication with the reservoir;
• placing each sorbent vessel of a first subset of the plurality of sorbent vessels into a gas collection phase by placing the sorbent material of the sorbent vessel in fluidic communication with the atmosphere and absorbing carbon dioxide;
• transitioning each sorbent vessel of a second subset of the plurality of sorbent vessels sequentially through N gas recovery stages of a gas recovery phase gradually increasing a sorbent vessel pressure and a sorbent vessel temperature, each gas recovery stage comprising the sorbent vessel receiving water vapor causing captured carbon dioxide to desorb from the sorbent material and the sorbent vessel releasing a product gas mixture comprising water vapor and carbon dioxide, wherein the first (N−1) gas recovery stages comprise placing the sorbent vessel in fluidic communication with the recovery subsystem at a downstream pressure and a different sorbent vessel in a heat recovery phase at an upstream pressure, wherein the Nth gas recovery stage comprises placing the sorbent vessel in fluidic communication with the condenser at the downstream pressure and the vaporizer at the upstream pressure, the upstream pressure being greater than the downstream pressure for each gas recovery stage, the upstream pressure of each gas recovery stage being greater than the upstream pressure of the previous gas recovery stage;
• and
• transitioning each sorbent vessel of a third subset of the plurality of sorbent vessels sequentially through (N−1) heat recovery stages of the heat recovery phase, gradually decreasing the sorbent vessel pressure and the sorbent vessel temperature, each heat recovery stage comprising placing the sorbent vessel in fluidic communication with a different sorbent vessel in the gas recovery phase at a heating pressure, the heating pressure decreasing in each subsequent heat recovery stage;
• wherein the gas collection phase, the gas recovery phase, and the heat recovery phase all exist at the same time within the plurality of sorbent vessels.