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US 12,516,002 B2Granted
Even carbon number paraffin composition and method of manufacturing same
AssigneeReg Synthetic Fuels, LLC
InventorsRamin Abhari, H. Lynn Tomlinson, Vladimir Gruver
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Abstract
Paraffin compositions including mainly even carbon number paraffins, and a method for manufacturing the same, is disclosed herein. In one embodiment, the method involves contacting naturally occurring fatty acid/glycerides with hydrogen in a slurry bubble column reactor containing bimetallic catalysts with equivalent particle diameters from about 10 to about 400 micron. The even carbon number compositions are particularly useful as phase change material.
Claims19
A method comprising:
- feeding naturally occurring fatty acids and esters to a reactor containing a gas phase and a catalyst in a slurry phase, where the catalyst comprises nickel, molybdenum, cobalt, tungsten, or a combination of any two or more thereof;
- at least partially hydrogenating/hydrogenolyzing the naturally occurring fatty acids and esters in the reactor;
- withdrawing a gas stream from the reactor and at least partially condensing the gas stream;
- separating the at least partially condensed gas stream into a second gas stream, a liquid water stream, and a liquid hydrocarbon stream;
- and
- processing the liquid hydrocarbon stream to recover at least a portion of even carbon numbered paraffins from the liquid hydrocarbon stream to produce a phase change material;
- wherein
- the reactor contains the catalyst in an amount of 1% to 30% based on dry bulk catalyst volume per total slurry volume;
- the reactor is controlled to be within 315° C. to 343° C. and within 200 psig to about 2,000 psig;
- the liquid hydrocarbon stream comprises at least 80 wt % even carbon number paraffins selected from the C12-C24 range;
- and
- the processing comprises distilling the liquid hydrocarbon stream.
9 more elements
Dependencies are inferred from the claim text.