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US 12,503,653 B2Granted
Process for the recycling of waste plastics based oil
AssigneeTotalenergies Onetech
InventorsBenjamin Biber, Christine Richardson, Delphine Minoux, Keith Nelson, Cindy Adam
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Abstract
The disclosure relates to the purification and treatment of oil produced from the liquefaction of waste polymer like for instance the pyrolysis of waste plastics via the polymerization of dienes prior to further treatments.
Claims18
A process for the purification of a liquified waste polymer to obtain a purified based oil, the process comprising:
- a) providing a feedstream (1) containing the liquified waste polymer, wherein said feedstream (1) contains at least 0.1 wt. % to at most 80.0 wt. % of dienes based on the total weight of said feedstream (1);
- c) performing a polymerization reaction on said feedstream (1) to obtain a first product stream (3) comprising an oligomeric product (33) and the liquified waste polymer, wherein the polymerization reaction is a cationic polymerisation performed in presence of an acidic catalyst;
- d) optionally performing a neutralization reaction of the first product stream (3) with a basic compound to obtain a neutralized product stream (4) and removing said basic compound from neutralized product stream (4) to obtain a second product stream (5);
- g) performing a separation to separate the oligomeric product (33) from the liquified waste polymer to obtain a purified liquified waste polymer (34);
- and
- i) performing a hydrotreating step on the purified liquified waste polymer (34) at a temperature of at least 200° C. to obtain a hydrotreated stream (9) being a purified based oil.
3 more elements
Dependencies are inferred from the claim text.