Diamond composite material and heat radiating member
AssigneeA.L.M.T. Corp.
InventorsTatsuya Morikawa, Takanori Kadokura, Kensuke Osawa
Life of this patent
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Abstract
Provided are a diamond composite material which is excellent in thermal conductivity, suitable as a material for a heat radiating member, and dense, the heat radiating member, and a method for producing a diamond composite material that can productively produce a diamond composite material which is excellent in wettability between diamond and metal and dense. The diamond composite material includes: a coated diamond particle including a diamond particle and a carbide layer covering a surface of the diamond particle and including an element of group 4 of the periodic table; and silver or a silver alloy binding such coated diamond particles together, with an oxygen content of 0.1 mass % or less.
Claims10
A diamond composite material comprising:
- a diamond particle;
- carbide layer covering a surface of the diamond particle and consisting essentially of TiC;
- and
- binding material consisting of silver binding the diamond particle covered by the carbide layer together;
- wherein the diamond composite material has an oxygen content of 0.1 mass % or less;
- wherein the diamond particle in the diamond composite material has a surface at which, except for silver, only the carbide layer is present;
- wherein the diamond composite material has a cold and hot cycle endurance of 95% or more at −60° C. to 250° C. and has a thermal conductivity degradation rate less than 5% after being heated to 800° C.;
- wherein the TiC is made from TiH2;
- and
- wherein the TiC is made by a method comprising:
- preparing a mixture powder including the diamond particle and TiH2 in a container;
- depositing silver on the mixture powder to form a stack of layers in the container;
- increasing a temperature of the container to about 200° C. to 300° C., wherein the silver discharges oxygen and oxygen is contained in the layer of the mixture powder;
- further increasing the temperature to about 500° C. to 600° C., wherein TiH2 is chemically decomposed into Ti, hydrogen, and oxygen, and wherein hydrogen forms water vapor and is discharged from the mixture powder;
- and
- further increasing the temperature, wherein the silver enters into the mixture powder, takes in Ti, and Ti contacts the diamond particle to form the TiC.
A method for producing a diamond composite material, the method comprising the steps of:
- preparing a mixture powder including a diamond particle and TiH2 in a container;
- depositing silver on the mixture powder to form a stack of layers in the container;
- increasing a temperature to about 200° C. to 300° C., wherein the silver powder discharges oxygen and oxygen is contained in the layer of the mixture powder;
- further increasing the temperature to about 500° C. to 600° C., wherein TiH2 is chemically decomposed into Ti, hydrogen, and oxygen, and hydrogen forms water vapor and is discharged from the mixture powder;
- and
- further increasing the temperature, wherein the silver enters in the mixture powder, takes in Ti, and Ti contacts the diamond particle to form the carbide layer covering the surface of the diamond particle, which consists essentially of TiC;
- wherein a gap formed between diamond particles covered by TiC is filled with silver,
- wherein the diamond composite material has an oxygen content of 0.1 mass % or less,
- wherein the diamond particle in the diamond composite material has a surface at which, except for silver, only a carbide layer consisting essentially of TiC is present,
- wherein the diamond composite material has a cold and hot cycle endurance of 95% or more at −60° C. to 250° C. and has a thermal conductivity degradation rate less than 5% after being heated to 800° C.
Dependencies are inferred from the claim text.