Three-dimensional organic sandwich chirality and its synthetic assembly

A pseudo C2-chiral molecule comprising a first, a second, and a third layer,

• wherein each of the layers are arranged in a nearly parallel fashion with chirality along a center plane,
• wherein each of the first, second, and third layers are at least one of:
• anti, syn, or both anti and syn isomers;
• wherein the pseudo C2-chiral molecule comprises any one of the following formulae (I), (ii), (III), or (IV):
• wherein, X is H, -Me, —OMe;
• and
• Y=—Cl, —N3, —NH2, —NHPh, -NHBn, -Me, -Et, -Bu, -iPr,
• or
• wherein, X is H, -Me, —OMe, or
• and
• R=—Cl, —N3, —NH2, —NHPh, -NHBn, -Me, -Et, -Bu, -iPr, —NH-Naph, —COCH3