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US 12,503,461 B2Granted
Pesticidally active heterocyclic derivatives with sulfur and sulfoximine containing substituents
AssigneeSyngenta Crop Protection AG
InventorsVikas Sikervar, Indira Sen, Michel Muehlebach, Sebastian Rendler, André Stoller, Daniel Emery, Anke Buchholz, Benedikt Kurtz
Life of this patent
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Abstract
Compounds of the formula (I), wherein the substituents are as defined in claim 1. Furthermore, the present invention relates to agrochemical compositions which comprise compounds of formula (I), to preparation of these compositions, and to the use of the compounds or compositions in agriculture or horticulture for combating, preventing or controlling animal pests, including arthropods and in particular insects or representatives of the order Acarina.
Claims29
A compound of formula (I)
- wherein
- G1 and G2 are, independently from each other, CH or N;
- G3 is NCH3 or O;
- R1 is C1-C6alkyl or C1-C6haloalkyl;
- R2 is H, C1-C6alkyl, C1-C6cycloalkyl, C1-C6haloalkyl, C(O)R3 or CN;
- R3 is C1-C6alkyl;
- Q is a radical selected from the group consisting of formula Qa and Qb
- wherein the arrow denotes the point of attachment to the carbon atom of the bicyclic ring;
- and wherein
- A is CH or N;
- X is S, SO or SO2;
- R4 is C1-C4alkyl;
- R5 is hydrogen or halogen;
- or
- R5 is a five- to six-membered aromatic ring system, linked via a ring carbon atom to the ring which contains the substituent A, said ring system is unsubstituted or is mono- or polysubstituted by substituents selected from the group consisting of halogen, cyano, C1-C4alkyl, C1-C4haloalkyl, C1-C4alkoxy, C1-C4haloalkoxy, C1-C4alkylsulfanyl, C1-C4alkylsulfinyl and C1-C4alkylsulfonyl;
- and said ring system optionally contains 1, 2 or 3 ring heteroatoms selected from the group consisting of nitrogen, oxygen and sulphur, where said ring system contains no more than one ring oxygen atom and not more than one ring sulfur atom;
- or
- R5 is a five-membered aromatic ring system linked via a ring nitrogen atom to the ring which contains the substituent A, said ring system is unsubstituted or is mono- or polysubstituted by substituents selected from the group consisting of halogen, cyano, C1-C4alkyl, C1-C4haloalkyl, C1-C4alkoxy, C1-C4haloalkoxy, C1-C4alkylsulfanyl, C1-C4alkylsulfinyl and C1-C4alkylsulfonyl;
- and said ring system contains 1, 2 or 3 ring heteroatoms selected from the group consisting of nitrogen, oxygen and sulphur, where said ring system contains at least one ring nitrogen atom but no more than one ring oxygen atom and not more than one ring sulfur atom;
- R6 is halogen, C1-C6haloalkyl, C3-C6cycloalkyl, C3-C6cycloalkyl monosubstituted by cyano, C3-C6alkyl monosubstituted by cyano, C1-C6alkoxy, C1-C6haloalkoxy, C1-C6alkoxy substituted with cyano, —N═S(O)R7R8, N(R9)C(═O)R10, N(R11)R12, or 2-pyridyloxy;
- or
- R6 is a five- to six-membered aromatic ring system, linked via a ring carbon atom to the ring which contains the substituent A, said ring system is unsubstituted or is mono- or polysubstituted by substituents selected from the group consisting of halogen, cyano, C1-C4alkyl, C1-C4haloalkyl, C1-C4alkoxy, C1-C4haloalkoxy, C1-C4alkylsulfanyl, C1-C4alkylsulfinyl and C1-C4alkylsulfonyl;
- and said ring system optionally contains 1, 2 or 3 ring heteroatoms selected from the group consisting of nitrogen, oxygen and sulphur, where said ring system contains no more than one ring oxygen atom and not more than one ring sulfur atom;
- or
- R6 is a five-membered aromatic ring system linked via a ring nitrogen atom to the ring which contains the substituent A, said ring system is unsubstituted or is mono- or polysubstituted by substituents selected from the group consisting of halogen, cyano, C1-C4alkyl, C1-C4haloalkyl, C1-C4alkoxy, C1-C4haloalkoxy, C1-C4alkylsulfanyl, C1-C4alkylsulfinyl and C1-C4alkylsulfonyl;
- and said ring system contains 1, 2 or 3 ring heteroatoms selected from the group consisting of nitrogen, oxygen and sulphur, where said ring system contains at least one ring nitrogen atom but no more than one ring oxygen atom and not more than one ring sulfur atom;
- R7 and R8 are, independently from each other, C1-C6alkyl;
- R9 is H or C1-C6alkyl;
- R10 is C1-C6alkyl or C3-C6cycloalkyl;
- R11 and R12 are, independently from each other, H or C1-C6alkyl;
- or an agrochemically acceptable salt, stereoisomer, enantiomer, tautomer or N-oxide of the compound of formula I.
28 more elements
Dependencies are inferred from the claim text.