Back to results
US 12,503,435 B2Granted
Aziridine functional compound
AssigneeCovestro (Netherlands) B.V.
InventorsGerardus Cornelis Overbeek, Patrick Johannes Maria Stals, Daan Van Der Zwaag, Alfred Jean Paul Bückmann, Josephus Christiaan Van Oorschot, Ronald Tennebroek
Life of this patent
Estimating the term…
Abstract
The present application relates to aziridine functional compounds with reduced genotoxicity and good crosslinking efficiency, for use in the preparation of, for example, coatings.
Claims19
An aziridine compound having:
- a) one or two of the following structural units A:
- wherein
- R1 is H;
- R2 and R4 are independently chosen from H or an aliphatic hydrocarbon group containing from 1 to 4 carbon atoms;
- R3 is an aliphatic hydrocarbon group containing from 1 to 4 carbon atoms;
- R′ and R″ are according to (1) or (2):
- (1) R′═H or an aliphatic hydrocarbon group containing from 1 to 14 carbon atoms, and
- R″=an aliphatic hydrocarbon group containing from 5 to 14 carbon atoms, a cycloaliphatic hydrocarbon group containing from 5 to 12 carbon atoms, an aromatic hydrocarbon group containing from 6 to 12 carbon atoms, CH2-O—(C═O)-R″, CH2-O-R″″, or CH2-(OCR″″HCR′″″H)n-OR″″″, whereby R′″ is an aliphatic hydrocarbon group containing from 4 to 14 carbon atoms and R″″ is an aliphatic hydrocarbon group containing from 1 to 14 carbon atoms or an aromatic hydrocarbon group containing from 6 to 12 carbon atoms, n being from 1 to 35, R″″′ independently being H or an aliphatic hydrocarbon group containing from 1 to 14 carbon atoms and R″″″ being an aliphatic hydrocarbon group containing from 1 to 4 carbon atoms,
- (2) R′ and R″ form together a saturated cycloaliphatic hydrocarbon group containing from 5 to 8 carbon atoms,
- R11 is H or an aliphatic hydrocarbon group containing from 1 to 14 carbon atoms, m is an integer from 1 to 6;
- b) one structural unit B:
- wherein
- p+q is an integer from 0 to 4;
- r is an integer from 0 to 2;
- X is NH or O or NR, wherein R contains at most 36 carbon atoms and optionally contains
- one or more heteroatoms in the chain;
- R5 and R6 are independently containing from 4 to 13 carbon atoms;
- R7 is a divalent group;
- and
- c) optionally one structural unit C:
- wherein
- Z is NH or O or NR wherein R contains at most 36 carbon atoms and optionally contains one or more heteroatoms in the chain;
- R8 is a monovalent group;
- and
- d) structural formula A-B-A or structural formula A-B-C;
- e) a molecular weight higher than 600 Daltons and at most 5000 Daltons, determined using MALDI-TOF mass spectroscopy;
- with the proviso that
- f) the mathematical sum of the molar mass of starting diisocyanate which provides carbodiimide functionality in the structural unit B+the molar mass of structural unit A+the molar mass of structural unit A is higher than 600 Daltons;
- and
- g) in case structural unit C is present, the mathematical sum of the molar mass of the starting diisocyanate which provides the carbodiimide functionality in the structural unit B+the molar mass of structural unit A+the molar mass of structural unit C is higher than 600 Daltons.
27 more elements
Dependencies are inferred from the claim text.