Process and plant for converting oxygenates to gasoline with improved gasoline yield and octane number as well as reduced durene levels
AssigneeTopsoe A/S
InventorsFinn Joensen, Arne Knudsen, Mathias Jørgensen, John Bøgild Hansen
Life of this patent
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Abstract
Process for converting an oxygenate feed stream, the process comprising the steps of: conducting the oxygenate feed stream to an oxygenate-to-gasoline reactor, suitably a methanol-to-gasoline reactor (MTG reactor) under the presence of a catalyst active for converting oxygenates in the oxygenate feed stream into a raw gasoline stream comprising C3-C4 paraffins and C5+ hydrocarbons; and adding an aromatic stream to the MTG reactor.
Claims20
A process for converting an oxygenate feed stream, the process comprising the steps of:
- conducting the oxygenate feed stream to an oxygenate-to-gasoline reactor under the presence of a fixed bed of catalyst active for converting oxygenates in the oxygenate feed stream into a raw gasoline stream comprising C3-C4 paraffins and C5+ hydrocarbons;
- said oxygenate feed stream being added to the oxygenate-to-gasoline reactor at a point upstream said fixed bed of catalyst;
- adding an aromatic stream to the oxygenate-to-gasoline reactor;
- wherein the oxygenate-to-gasoline reactor is a methanol-to-gasoline (MTG) reactor having arranged along its length a fixed bed or a plurality of successive fixed beds comprising the catalyst, the extension along the length of the MTG reactor of said fixed bed or plurality of successive fixed beds defining a total bed length;
- the process further comprising:
- operating the MTG reactor adiabatically and adding the aromatic stream at 40-80% of the total bed length;
- separating from the raw gasoline stream a gasoline product stream comprising the C5+ hydrocarbons and a stream comprising C3-C4 paraffins;
- and
- conducting the stream comprising C3-C4 paraffins or a portion thereof to an upgrading reactor under the presence of a catalyst active for converting the C3-C4 paraffins into the aromatic stream, in which the aromatic stream comprises any of benzene, toluene or xylene, or combinations thereof.
A process for converting an oxygenate feed stream, the process comprising the steps of:
- conducting the oxygenate feed stream to an oxygenate-to-gasoline reactor under the presence of a fixed bed of catalyst active for converting oxygenates in the oxygenate feed stream into a raw gasoline stream comprising C3-C4 paraffins and C5+ hydrocarbons;
- said oxygenate feed stream being added to the oxygenate-to-gasoline reactor at a point upstream said fixed bed of catalyst;
- adding an aromatic stream to the oxygenate-to-gasoline reactor;
- wherein the oxygenate-to-gasoline reactor is a methanol-to-gasoline (MTG) reactor having arranged along its length a fixed bed or a plurality of successive fixed beds comprising the catalyst, the extension along the length of the MTG reactor of said fixed bed or plurality of successive fixed beds defining a total bed length;
- the process further comprising:
- operating the MTG reactor adiabatically and adding the aromatic stream at 40-80% of the total bed length;
- wherein the aromatic stream is a benzene-rich stream (B-rich stream) which is separated from an aromatic stream comprising BTX.
Dependencies are inferred from the claim text.