Process for producing a polyurethane composition
AssigneeBASF SE
InventorsStephan Salzinger, Robert Reichardt
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Abstract
The presently claimed invention provides a continuous process for preparing a polyurethane composition which behaves as a rheology modifier upon addition to paint and coating formulations. The present process employs mixers for homogenization of highly viscous polyurethane polymers and by adjusting the process parameters and reactor conditions in specified ranges obtained a polyurethane composition. The polyurethane composition obtained from the process of the present invention is used as thickener in water-borne paint and coating formulations.
Claims19
A continuous process for preparing a polyurethane composition comprising the steps of:
- (A) mixing
- (a) at least one polyalkylene glycol having a water content in the range of ≥0.0 to ≤0.1 wt.-% by weight of the polyalkylene glycol,
- (b) at least one compound selected from the group consisting of C4 to C30 alcohols, C4 to C30 alcohol alkoxylates and C4 to C30 alkyl phenol alkoxylates,
- (c) at least one polyisocyanate, and
- (d) at least one catalyst,
- at a temperature in the range of ≥50° C. to ≤80° C. to obtain a reaction feed stream,
- (B) subjecting the reaction feed stream of step (A) in at least one reactor to a temperature in the range of ≥80° C. to ≤150° C. and a residence time in the range of 0.05 h to ≤4 h to obtain a polyurethane;
- wherein the viscosity of the polyurethane obtained in step (B) is in the range of ≥1 Pa·s to ≤5000 Pa·s at a temperature of 100° C.;
- and
- (C) adding water to the polyurethane of step (B) to obtain a polyurethane composition, characterized in that the difference between the temperature in step (B) and the temperature in step (A) is in the range of ≥10° C. to ≤50° C.;
- wherein, step (A) and step (B), independent of each other, is carried out in the static mixer.
Dependencies are inferred from the claim text.