Click-chemistry compatible structures, click-chemistry functionalized structures, and materials and methods for making the same

A method, comprising:

• adding one or more pore-forming compounds to an additive manufacturing resin comprising one or more photo polymerizable compounds,
• wherein the one or more pore-forming compounds are each independently configured to create pores in a three-dimensional structure defined by a three-dimensional pattern, wherein the photo polymerizable compound comprises at least one click-chemistry compatible functional group,
• wherein the at least one click-chemistry compatible functional group is distinct from one or more functional groups that convey photo polymerizable capability on the photo polymerizable compound;
• and
• exposing one or more portions of the additive manufacturing resin including the one or more pore-forming compounds to light to form the three-dimensional structure;
• and
• removing the one or more pore-forming compounds for rendering the three-dimensional structure porous;
• wherein the light includes a wavelength configured to cause some or all of the one or more photo polymerizable compounds in the additive manufacturing resin to polymerize;
• and
• wherein one or more surfaces of at least some pores of the three-dimensional structure are functionalized with one or more of the at least one click-chemistry compatible functional group.

A method, comprising:

• exposing one or more portions of an additive manufacturing resin comprising one or more photo polymerizable compounds to light to form a three-dimensional structure, the one or more photo polymerizable compounds having at least one click-chemistry compatible functional group configured to participate in a click-chemistry reaction,
• wherein the at least one click-chemistry compatible functional group is distinct from one or more functional groups that convey photo polymerizable capability on the photo polymerizable compound,
• wherein the light includes a wavelength configured to cause crosslinking of the one or more photo polymerizable compounds in the additive manufacturing resin to thereby polymerize the one or more photo polymerizable compounds, and
• wherein one or more surfaces of the three-dimensional structure are functionalized with the at least one click-chemistry compatible functional group.