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US 12,486,369 B2Granted
Polyimide-based film having excellent surface evenness and method for producing same
AssigneeKolon Industries, Inc.
InventorsHyo Jun Park, Jong Won Yang
Life of this patent
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Abstract
Disclosed are a polyimide-based film and a method of producing the same, and more particularly, a polyimide-based film having excellent surface evenness and suppressed waviness due to low Kc of 1.55 or less and a method of producing the same.
Claims16
A polyimide-based film having a Kc value of 1.55 or less,
- wherein the polyimide-based film is produced by:
- preparing a liquid resin composition using monomer components including dianhydride and diamine,
- producing a gel-state film using the liquid resin composition,
- first drying the gel-state film at a temperature of 50 to 150° C. at a wind speed of 0 m/s or less for a drying period of 2 to 20 minutes, and
- second drying the gel-state film at a wind speed of 1.0 to 5.0 m/s at 70 to 140° C. after the first drying,
- wherein the Kc value is a curvature parameter measured for a waviness having a wavelength range of 1.0 to 3.0 mm by phase stepped deflectometry,
- wherein a polyimide-based film sample having a width of 15 cm×a length of 15 cm×thickness of 80 μm is used for measuring K, and
- a measuring device is in a curvature mode K with 1.0 to 3.0 mm wavelength range, and a sheet of black matte paper is placed on a surface plate in a dark room, the sample to be measured is placed thereon, the Kc value is measured 10 times, and the average value is used as the Kc value of the sample,
- wherein the polyimide-based film is produced from monomer components including dianhydride and diamine,
- the dianhydride comprises at least one selected from 2,2-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride, 3,3′,4,4′-biphenyl tetracarboxylic dianhydride, 4-(2,5-dioxotetrahydrofuran-3-yl)-1,2,3,4-tetrahydronaphthalene-1,2-dicarboxylic anhydride, pyromellitic dianhydride, 3,3′,4,4′-benzophenone tetracarboxylic dianhydride, 4,4′-oxydiphthalic anhydride, 4,4′-(3,4-bisdicarboxyphenoxy-diphenyl sulfide dianhydride, 3,3′,4,4′-diphenylsulfonetetracarboxylic dianhydride, 4,4′-(4,4′-Isopropylidenediphenoxy)bis(phthalic anhydride), cyclobutane-1,2,3,4-tetracarboxylic dianhydride, 1,2,3,4-cyclopentane-tetracarboxylic dianhydride, 1,2,4,5-cyclohexanetetracarboxylic dianhydride, and dicyclohexyl-3,4,3′,4′-tetracarboxylic dianhydride,
- the diamine comprises at least one selected from 3,4-oxydianiline, 4,4′-oxydianiline, p-phenylenediamine, m-phenylenediamine, 4,4-methylenedianiline, 3,3-methylenedianiline, 1,3-Bis(3-aminophenoxy)benzene, 1,3-Bis(4-aminophenoxy)benzene, 2,2′-bis[4-(4-aminophenoxy) phenyl] hexafluoropropane, 2,2′-bis(3-aminophenyl)hexafluoropropane, 2,2′-bis(4-aminophenyl) hexafluoropropane, bis(4-aminophenyl)sulfone, bis(3-aminophenyl)sulfone, 2,2′-bis(trifluoromethyl)benzidine, 1,3-cyclohexanediamine, 1,4-cyclohexanediamine, 2,2-bis[4-(4-aminophenoxy)phenyl]propane, 2,2-bis(3-amino-4-hydroxyphenyl)hexafluoropropane, bis[4-(4-aminophenoxy)phenyl] sulfone, bis[4-(3-aminophenoxy)phenyl] sulfone, 9,9-bis(4-aminophenyl)fluorene and 9,9-bis(4-amino-3-fluorophenyl)fluorene.
8 more elements
A method of producing a polyimide-based film comprising:
- preparing a liquid resin composition using monomer components including dianhydride and diamine;
- producing a gel-state film using the liquid resin composition;
- first drying the gel-state film at a temperature of 50 to 150° C. at a wind speed of 1.0 m/s or less for a drying period of 2 to 20 minutes;
- and
- second drying the gel-state film at a wind speed of 1.0 to 5.0 m/s at 70 to 140° C. after the first drying,
- wherein, in the first drying, the drying coefficient conditions according to the following Equations 1 and 2 are satisfied when the temperature is A° C., the wind speed is B m/s and the drying period is T minutes:
- 0.5≤[(A−40)×B×T]/100≤10 [Equation 1]
- 2≤[(A−40)×T]/100≤10. [Equation 2]
5 more elements
Dependencies are inferred from the claim text.