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US 12,486,351 B2Granted
Solid surface materials with polyurethane matrix
AssigneeCovestro Deutschland AG
InventorsAnn-Christin Bijlard, Lukas Breuers, Joan Miguel Garcia Martinez
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Abstract
The present invention relates to polyurethane based solid surface materials with improved dimensional stability which can be made using conventional inorganic fillers without pre-treatment of the fillers.
Claims12
A polymerizable composition comprising
- (i) at least one polyol A1 having an OH-content of at least 25 wt.-%, wherein the at least one polyol A1 is selected from the group consisting of glycerol, propanediol, butanediol, 1,2,10-decanetriol, 1,2,8-octanetriol, 1,2,3-trihydroxybenzene, 1,1,1-trimethylolpropane, 1,1,1-trimethylolethane, penthaerythrol and sugar polyols;
- (ii) at least one polyisocyanate A2 comprising at least 60 wt.-% of aliphatic polyisocyanates;
- (iii) at least one organic filler B1;
- (iv) at least one inorganic filler B2, wherein the inorganic filler B2 is not dried and comprises a water content of at least 0.15 wt.-%;
- and
- (v) expandable microspheres;
- wherein the polyol A1 makes up at least 95 wt.-% of all hydroxyl-functional compounds in the polymerizable composition, and
- wherein the polymerizable composition is for reaction injection molding.
5 more elements
A solid surface material comprising
- a) a polyurethane matrix comprising as building blocks
- (i) at least one polyol A1 having an OH-content of at least 25 wt.-%, wherein the at least one polyol A1 is selected from the group consisting of glycerol, propanediol, butanediol, 1,2,10-decanetriol, 1,2,8-octanetriol, 1,2,3-trihydroxybenzene, 1,1,1-trimethylolpropane, 1,1,1-trimethylolethane, penthaerythrol and sugar polyols;
- and
- (ii) at least one polyisocyanate A2 comprising at least 60 wt.-% of aliphatic polyisocyanates;
- wherein the polyol A1 makes up at least 95 wt.-% of all hydroxyl-functional compounds in the polyurethane matrix;
- and
- b) at least one organic filler B1, at least one inorganic filler B2, wherein the inorganic filler B2 is not dried and comprises a water content of at least 0.15 wt.-%, and expandable microspheres,
- wherein the solid surface material is formed by a reaction molding process.
5 more elements
A method for manufacturing a solid surface material comprising the steps of
- a) mixing of (i) at least one polyol A1 having an OH-content of at least 25 wt.-%, wherein the at least one polyol A1 is selected from the group consisting of glycerol, propanediol, butanediol, 1,2,10-decanetriol, 1,2,8-octanetriol, 1,2,3-trihydroxybenzene, 1,1,1-trimethylolpropane, 1,1,1-trimethylolethane, penthaerythrol and sugar polyols, (ii) at least one polyisocyanate A2 comprising at least 60 wt.-% of aliphatic and cycloaliphatic polyisocyanates, (iii) at least one organic filler B1, (iv) at least one inorganic filler B2, wherein the inorganic filler B2 is not dried and comprises a water content of at least 0.15 wt.-%, and (v) expandable microspheres;
- wherein the polyol A1 makes up at least 80 wt.-% of all hydroxyl-functional compounds in the reaction mixture obtained in method step a);
- b) filling of the reaction mixture obtained in method step a) into a closed mold;
- and
- c) curing of the reaction mixture,
- wherein the method is a reaction molding process.
3 more elements
Dependencies are inferred from the claim text.