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US 12,485,404 B2Granted
Process for producing an oligomerization catalyst having a hydrothermal treatment step
AssigneeEvonik Oxeno GmbH
InventorsJohannes Knossalla, Thomas Quandt, Robert Franke
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Abstract
A process for producing an oligomerization catalyst includes hydrothermal treatment. An oligomerization catalyst produced by the process is useful for the oligomerization of C2 to C12 olefins.
Claims20
A process for producing a nickel-containing oligomerization catalyst, the process comprising:
- a) producing a mixture comprising
- amorphous aluminium silicate that comprises 1% to 45% by weight of aluminium oxide and 55% to 99% by weight of silicon dioxide,
- optionally, an Al-containing and Si-free binder or an Al-free and Si-containing binder,
- a nickel source that comprises a nickel compound, and
- water,
- wherein a liquid component in the mixture is not more than 1.5 times a total pore volume (TPV) of the aluminium silicate and of the optional binder, the TPV being determined by nitrogen adsorption in accordance with DIN 66134;
- b) subjecting the mixture thus produced to a hydrothermal treatment, the hydrothermal treatment taking place at a temperature in a range from 75° C. to 180° C.;
- c) drying the mixture obtained in b), the drying rate in c) being higher than a drying rate in b);
- and
- d) calcining the mixture dried in c) to produce the oligomerization catalyst, wherein the drying rate in c) is at least twice as high as the drying rate in b).
7 more elements
Dependencies are inferred from the claim text.