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US 12,466,922 B2Granted
Film extrusion composition and associated extruded film, metallized film, and capacitor
AssigneeShpp Global Technologies B.V.
InventorsAndrew Thomas Pingitore, James Alan Mahood, Matthew Frank Niemeyer
Life of this patent
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Abstract
A film extrusion composition includes specific amounts of a heat-resistant copolycarbonate, a slip agent, and a particulate crosslinked polymethylsilsesquioxane having particles of a specific size. An extruded film prepared from the film extrusion composition exhibits a beneficial balance of telescoping, blocking, and dielectric properties. The extruded film is useful for forming electrostatic film capacitors.
Claims15
A film extrusion composition comprising, based on the total weight of the film extrusion composition:
- 50 to 99.35 weight percent of a copolycarbonate comprising, based on 100 mole percent total carbonate units in the copolycarbonate,
- 20 to 60 mole percent of first carbonate units having the structure
- wherein R1 is a C6-C16 divalent aromatic group;
- 40 to 80 mole percent of second carbonate units having the structure
- wherein R2 is a C17-C40 divalent aromatic group having the structure
- wherein Rf and Rg are each independently at each occurrence C1-C12 alkyl, C1-C12 alkoxyl, or C2-C12 alkenyl;
- each Rh is hydrogen or two occurrence of Rh combine with the carbon atom to which they are attached to form a carbonyl group;
- each occurrence of Ri is independently C1-C6 alkyl;
- Rj is hydrogen, C1-C6 alkyl, or phenyl optionally substituted with 1, 2, 3, 4, or 5 C1-C6 alkyl groups;
- Rk is independently at each occurrence C1-C3 alkyl or phenyl, preferably methyl;
- Xb is C6-C12 arylene, C4-C18 cycloalkylene, C4-C18 cycloalkylidene, or —C(Rm)(Rn)— wherein Rm is hydrogen, C1-C12 alkyl, or C6-C12 aryl, and Rn is C6-C10 alkyl, C6-C8 cycloalkyl, or C6-C12 aryl, or Xb is -(Qa)x-G-(Qb)y-, wherein Qa and Qb are each independently C1-C3 alkylene, G is C3-C10 cycloalkylene, x is zero or 1, and y is zero or 1;
- and j, m, and n are each independently zero, 1, 2, 3, or 4;
- and
- 0 mole percent of third carbonate units, each third carbonate unit comprising a divalent carbonate group and a divalent polysiloxane group, the divalent polysiloxane group comprising 5 to 60 diorganosiloxane units having the structure
- wherein each occurrence of R3 is independently a C1-C13 hydrocarbyl group;
- 0.1 to 6 weight percent of a slip agent selected from the group consisting of pentaerythritol tetrastearate, dipentaerythritol hexastearate, glycerol tristearate, high density polyethylenes, polymethylpentenes, poly(carbonate-siloxane) s, and combinations thereof;
- and
- 0.55 to 0.8 weight percent of a particulate crosslinked polymethylsilsesquioxane having a number-based mean equivalent spherical diameter of 0.5 to 4 micrometers determined by electrical sensing zone method according to ISO 13319-1:2021.
15 more elements
Dependencies are inferred from the claim text.