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US 12,460,150 B1Granted
Low-ash lubricating compositions
AssigneeAfton Chemical Corporation
InventorsMariah Parker, Kenneth Garelick
Life of this patent
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Abstract
This disclosure describes low-ash lubricating composition achieving the same or better performance of higher ash compositions by including selected antiwear system with ashless phosphorus-containing antiwear compounds and select detergent systems matching TBN contributions to the antiwear systems.
Claims17
A passenger car lubricating composition having a low sulfated ash content, the passenger car lubricating composition comprising:
- one or more base oils of lubricating viscosity;
- an antiwear system including one or more ashless phosphorus-containing antiwear compounds and, optionally, one or more metal-containing antiwear compounds, and wherein a phosphorus weight ratio of phosphorus from the one or more ashless antiwear compounds to phosphorus from the one or more optional metal-containing antiwear compounds is about 50:50 to about 100:0, wherein the ashless phosphorus-containing antiwear additive is a triester of a dithiophosphate having two oxygen ester moieties and a sulfur ester moiety, wherein the ashless phosphorus-containing antiwear additive has a molecular weight of at least about 490 g/mol, and wherein each oxygen ester is derived from 4-methyl-2-pentyl alcohol and the sulfur ester is derived from dibutyl maleate;
- a sulfated ash content of about 0.75 weight percent or less as measured pursuant to ASTM D874;
- about 700 ppm or less of total phosphorus contributed by the one or more ashless phosphorus-containing antiwear compounds and the optional one or more metal-containing antiwear compounds;
- a detergent system having a weight ratio of magnesium-to-calcium of about 2.0 or less;
- and
- a TBN ratio of TBN measured per ASTM D4739 relative to TBN measured per ASTM D2896 of at least about 60 percent.
4 more elements
Dependencies are inferred from the claim text.