Process for producing calcium silicate hydrate
AssigneeBASF SE
InventorsMichael Dietzsch, Christoph Hesse
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Abstract
The present invention relates to a process for producing calcium silicate hydrate under hydrothermal conditions, wherein an organic compound is added in at least one of the process steps and wherein the organic compound has a molecular weight of 100 to 600 g/mol and from 0.02 to 0.035 functional groups per gram of the organic compound, wherein the functional groups being selected from —OH, —COOH, —COOMa, —SO3H or —SO3Ma, or —C(═O)H, wherein M is hydrogen, a mono-, di- or trivalent metal cation, ammonium ion or an organic amine radical and a is ⅓, ½ or 1. Further the invention is directed to the calcium silicate hydrate produceable according to the process of the present invention and its use as curing accelerator for hydraulic binders.
Claims13
A process for producing a composition comprising calcium silicate hydrate, the process comprising the steps of
- a) reacting a calcium hydroxide source with a silicon dioxide source in the presence of water under hydrothermal conditions at a temperature in the range of from 100° C. to 400° C. for a period of from 1 hours to 30 hours, forming a process product from step a);
- b) bringing in contact
- i) the process product from step a) and
- ii) a water-soluble polymeric dispersant
- in an aqueous medium while introducing kinetic energy, forming a process product of step b;
- and optionally,
- c) adding the process product of step b) to a building material mixture comprising a hydraulic binder or a latent hydraulic binder;
- wherein an organic compound is added in at least one of the steps a), b) or to the process product after completion of step b),
- wherein the organic compound has a molecular weight of 100 to 600 g/mol and from 0.015 to 0.035 functional groups per gram of the organic compound, wherein the functional groups being selected from —OH, —COOH, —COOMa, —SO3H, —SO3Ma, or —C(═O)H, wherein M is hydrogen, a mono-, di- or trivalent metal cation, ammonium ion or an organic amine radical and a is ⅓, ½ or 1,
- wherein when the organic compound is added in step a), the temperature in step a) is chosen below the melting point of the organic compound used and
- wherein when the organic compound is added to the process product after completion of step b), and if the process comprises a step c), the organic compound is added between steps b) and c).
A calcium silicate hydrate composition comprising
- 60-85% by weight of calcium silicate hydrate
- 10-20% by weight of water-soluble polymeric dispersant
- 0.4-3.6% by weight of the organic compound
- based on the dry weight of the composition, wherein the organic compound has a molecular weight of 100 to 600 g/mol and from 0.015 to 0.035 functional groups per gram of the organic compound, wherein the functional groups being selected from —OH, —COOH, —COOMa, —SO3H, —SO3Ma or —C(═O) H, wherein M is hydrogen, a mono-, di- or trivalent metal cation, ammonium ion or an organic amine radical and a is ⅓, ½ or 1.
Dependencies are inferred from the claim text.