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US 12,448,700 B2Granted
Methods for low energy inorganic material synthesis
AssigneeRutgers, The State University of New Jersey
InventorsRichard E. Riman, Daniel Kopp
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Abstract
The present invention relates to solvothermal vapor synthesis methods for the crystallization of a phase from a mixture of selected inorganic or organic precursors in an unsaturated vapor-phase reaction medium.
Claims20
A method of synthesizing an inorganic product, the method comprising:
- providing one or more inorganic compound sources of reaction elements, wherein said reaction elements react to form one or more inorganic products in a sealed reaction vessel;
- providing a reaction medium comprising water or an organic species or an inorganic species that forms an unsaturated phase at a predetermined temperature and non-standard state pressure;
- adding the reaction elements and reaction medium to the reaction vessel;
- forming an unsaturated vapor phase of the reaction medium at a predetermined temperature and non-standard state pressure, wherein the reaction vessel has a total pressure of greater than 1 atm;
- and
- reacting the reaction elements in said unsaturated vapor phase of the reaction medium to form at least one inorganic reaction product;
- wherein one or more or the temperature, unsaturated vapor pressure, and partial pressure of any gases added or produced are selected to reduce the total non-standard state change in Gibbs free energy of the chemical reaction for the formation of at least one inorganic reaction product to less than or equal to zero.
4 more elements
Dependencies are inferred from the claim text.