Production of hydrocarbon fuels from lignin-derived materials
AssigneeHis Majesty the King In Right of Canada, AS Represented By the Minister of Natural Resources
InventorsJacques Monnier, Yi Zhang
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Abstract
A continuous process for producing hydrocarbon products, such as jet fuel, diesel, and naphtha, from lignin-derived materials comprising lignin oligomers, via hydrodeoxygenation in presence of catalysts under hydrogen pressure. These hydrocarbon products can then be fractionated into fuels such as naphtha, jet fuel, or diesel. Preferably, the jet fuel and diesel meet the corresponding fuel standards. Preferably, the naphtha meets key specifications of the corresponding gasoline and naphtha standards. Because lignin-derived materials are produced from biomass, the hydrocarbon products, including the jet fuel, diesel, and naphtha produced by this process, may contain up to 100% biogenic carbon.
Claims19
A process for producing one or more hydrocarbon fuels, said process comprising:
- (a) providing a lignin-derived material as a feedstock, said lignin-derived material comprising lignin oligomers;
- (b) placing said feedstock into a feedstock stream;
- (c) hydrodeoxygenating said feedstock stream in a first continuous reactor by contacting said feedstock stream with gaseous hydrogen in the presence of a first catalyst to thereby produce a partially hydrodeoxygenated intermediate that exits said first continuous reactor;
- (d) separating gaseous and aqueous by-products from said partially hydrodeoxygenated intermediate to thereby obtain an organic intermediate;
- (e) hydrodeoxygenating said organic intermediate in a second continuous reactor by contacting said organic intermediate with gaseous hydrogen in the presence of a second catalyst to thereby produce a hydrodeoxygenated product that exits said second continuous reactor;
- (f) separating second-stage by-products from said hydrodeoxygenated product to thereby produce a hydrocarbon product;
- and
- (g) fractionating said hydrocarbon product to obtain said one or more hydrocarbon fuels,
- wherein said process is continuous, and wherein each of said step (c) and said step (e) are conducted under operating conditions comprising:
- a temperature in the range of about 350° C. to about 450° C.;
- and
- a hydrogen gauge pressure in the range of about 6 MPa to about 18 MPa.
Dependencies are inferred from the claim text.