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US 12,448,549 B2Granted
VAE dispersion for D3 wood adhesives
AssigneeCelanese International Corporation
InventorsFrank Bertram Polzer, Daniela Hardt
Life of this patent
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Abstract
Disclosed herein are D3 water-resistant adhesive compositions comprising aqueous copolymer dispersions and uses of such compositions. The compositions are useful as binders for porous and semi-porous substrates such as wood, paper, and/or board. Importantly, the adhesive compositions have very low formaldehyde content and little or no plasticizer content.
Claims20
An adhesive composition comprising an aqueous copolymer dispersion comprising:
- at least one copolymer of at least one vinyl ester of a C1-13 alkanoic acid co-monomer, at least one alpha-olefin co-monomer, and at least one auxiliary co-monomer selected from the group consisting of N-alkylol-containing co-monomers, unsaturated silane co-monomers, glycidyl ether/epoxy co-monomers, cyclic ureido co-monomers, acrylamido glycolic acid co-monomers, and combinations thereof;
- and
- at least one stabilizer selected from the group of polyvinyl alcohols, wherein the group of polyvinyl alcohols comprise a first group of polyvinyl alcohols having a degree of hydrolysis greater than 90 mol % and a second group of polyvinyl alcohols having a degree of hydrolysis equal to or less than 90 mol %, wherein the first group of polyvinyl alcohols having a degree of hydrolysis greater than 90 mol % has a viscosity from 2 mPa*s to 35 mPa*s;
- wherein the copolymer dispersion comprises, based on dried polymer, from 60 to 95 wt % of the C1-13 alkanoic acid, from 1 to 35 wt % of the alpha-olefin, and from 0.1 to 5 wt % of the at least one auxiliary co-monomer, and from 0.5 to 20 wt % of the at least one stabilizer;
- and
- wherein the copolymer dispersion has a viscosity from 2000 mPa*s to 30,000 mPa*s at 25 to 65% solids;
- wherein the adhesive composition has an MFFT lower than 15° C., a D3-3 bond strength greater than 2 N/mm2 according to DIN EN 204:2016, and a bond strength greater than 4 N/mm2 according to DIN EN 14257:2019 (WATT91).
4 more elements
Dependencies are inferred from the claim text.