US 12,448,508 B2 · Crosslinking of aromatic polymers for anion exchange membranes

Abstract

An ion exchange membrane material is composed of a crosslinked polymer network including a first poly(styrene-b-ethylene-r-butylene-b-styrene) triblock copolymer (SEBS), and second SEBS, and a linker crosslinking the first SEBS and the second SEBS. At least one phenyl group from the first SEBS and the second SEBS is functionalized with an alkyl group, and the carbon at the benzylic position of these alkyl groups is saturated with at least two additional alkyl groups. The linker is a diamine bound to the alkyl functional groups. The ion exchange membrane material is made via a substantially simultaneous quaternization and crosslinking reaction between the diamine linker and SEBS functionalized with alkyl halide groups. Increasing concentration of crosslinker in produces membranes with reduced water uptake, leading to an expectation of enhanced stability under hydrated conditions and greater durability. Advantageously, this reduction in water uptake came with little change to ion exchange capacity.

Claims12

Dependent claims

An ion exchange membrane material comprising:

a crosslinked polymer network including:
a first polymeric chain, wherein the first polymeric chain comprises:
a first poly(styrene-b-ethylene-r-butylene-b-styrene) triblock copolymer (SEBS), wherein at least one phenyl group of the first SEBS is functionalized with a first alkyl group, and the carbon at the benzylic position of the first alkyl group is saturated with at least two additional alkyl groups;
a second polymeric chain, wherein the second polymeric chain comprises:
a second poly(styrene-b-ethylene-r-butylene-b-styrene) triblock copolymer (SEBS), wherein at least one phenyl group of the second SEBS is functionalized with a second alkyl group, and the carbon at the benzylic position of the second alkyl group is saturated with at least two additional alkyl groups;
and
a diamine linker bound to the first alkyl group and the second alkyl group,
wherein the first polymeric chain, the second polymeric chain, and/or the crosslinked polymer network comprises a polyaromatic polymer, a copolymer, a block copolymer, or a combination thereof.

5 more elements

Dependencies are inferred from the claim text.

Crosslinking of aromatic polymers for anion exchange membranes

Life of this patent

Crosslinking of aromatic polymers for anion exchange membranes

Life of this patent

Abstract

Claims12