Back to results
US 12,448,479 B2Granted
Radiation curable and printable composition
AssigneeHenkel AG & Co. KGaA
InventorsSebastien Lanau, Andrea Gutacker, Johann Klein, Claudia Meckel-Jonas, Ralf Dunekake, Markus Bonigut
Life of this patent
Estimating the term…
Abstract
The present invention relates to radiation of dual radiation/moisture curable compositions based on (meth)acrylate- and silane-terminated polymers that can be used as 3D printing materials and provide isotropic and elastomeric properties. The invention further relates to the use thereof as 3D printing materials and printing methods using said compositions.
Claims17
A reactive curable printable composition, comprising:
- (i) at least one polymer A comprising at least one terminal group of formula (I):
- -A1-C(═O)—CR1═CH2 (I),
- wherein:
- A1 comprises a substituted or unsubstituted amide, carbamate, urethane, urea, imino, siloxane, carboxylate, carbamoyl, amidino, carbonate, sulfonate or sulfinate group;
- R1 is selected from H and C1-C4 alkyl;
- wherein the polymer backbone of the at least one polymer A is a polyoxyalkylene;
- and
- (ii) at least one filler that is configured to modify one or more rheological properties of the composition,
- wherein the composition is in a form of a paste and has a yield stress of greater than 25, wherein the yield stress is calculated using the formula:
- τ
- 1
- 2
- =
- k
- oc
- 1
- 2
- +
- k
- c
- 1
- 2
-
- γ
- 1
- 2
- ,
- wherein τ (tau) is shear stress, koc is Casson yield stress, kc is Casson plastic viscosity and γ (gamma) is shear rate, wherein the shear rate and the shear stress are measured using BS EN ISO 3219:1995, wherein the measuring conditions are as follows:
- Geometry:
- 25 mm plate/plate geometry, Gap:
- 0.25 mm, F=0N, under nitrogen, 25° C., Shear rate 0.3-40 s−1, wherein Casson's model is used for extrapolation.
28 more elements
Dependencies are inferred from the claim text.