Refrigerant-containing composition, use of same, refrigerator having same, operation method for said refrigerator, and refrigeration cycle device equipped with same
AssigneeDaikin Industries, Ltd.
InventorsMitsushi Itano, Shun Ohkubo, Daisuke Karube
Life of this patent
Estimating the term…
Abstract
The present invention addresses a problem of providing a mixed refrigerant that combines three kinds of performances of having a refrigeration capacity (this may also be referred to as a cooling capacity) and of having a coefficient of performance (COP) equivalent to those of R410A, and of having a sufficiently small GWP. As a means for solving the problem, provided is a refrigerant-containing composition, wherein the refrigerant contains trans-1,2-difluoroethylene (HFO-1132 (E)), trifluoroethylene (HFO-1123) and 2,3,3,3-tetrafluoro-1-propene (R1234yf), and R32.
Claims11
A composition comprising a refrigerant,
- wherein the refrigerant contains trans-1,2-difluoroethylene (HFO-1132 (E)), trifluoroethylene (HFO-1123) and 2,3,3,3-tetrafluoro-1-propene (R1234yf), and difluoromethane (R32), and
- wherein, in the refrigerant, when mass percentages of HFO-1132 (E), HFO-1123 and R1234yf, and R32, based on their sum are defined as x, y and z, and a, respectively, in a ternary composition diagram in which a sum of HFO-1132 (E), HFO-1123 and R1234yf is (100−a) % by mass, coordinates (x,y,z) are:
- in a case of 0<a≤11.1,
- within a range of a figure surrounded by lines JL, LM, MN, NK′, K′B, BD′, D′C, and CJ connecting each of eight points:
- point J (100−a−y, −0.0049a2−0.0355a+52.9, 0.0);
- point L (−0.0217a2−0.9307a+63.0, 95.0−a−x, 5.0);
- point M (0.0292a2−1.7567a+68.9, −0.0194a2+0.8278a+16.1, 100−a−x−y);
- point N (0.043a2−2.1084a+66.9, −0.0268a2+0.6129a+9.4, 100−a−x−y);
- point K′ (−0.051a2+0.0929a+25.95, 100−a−x−z, −0.0191a2+1.0231a+32.4);
- point B (0.0, 0.0144a2−1.6377a+58.7, 100−a−y);
- point D′ (0.0, 0.0224a2+0.968a+75.4, 100−a−y);
- and
- point C (−0.2304a2−0.4062a+32.9, 100−a−x, 0.0),
- or on the lines JL, LM, MN, NK′, K′B, and D′C (except for point B, point D′, point C, and point J);
- in a case of 11.1<a≤18.2,
- within a range of a figure surrounded by lines JL, LM, MN, NK′, K′B, BW, and WJ connecting each of seven points:
- point J (100−a−y, −0.0243a2+0.4161a+50.275, 0.0);
- point L (0.0187a2−1.4492a+63.783, 95.0−a−x, 5.0);
- point M (0.0197a2−1.5633a+67.924, −0.0611a2+1.9179a+9.1435, 100−a−x−y);
- point N (0.009a2−1.3469a+62.647, −0.0225a2+0.5467a+9.6045, 100−a−x−y);
- point K′ (0.0341a2−2.1977a+61.187, 100−a−x−z, −0.0105a2+0.8577a+33.177);
- point B (0.0, 0.0075a2−1.5156a+58.199, 100−a−y);
- and
- point W (0.0, 100−a, 0.0),
- or on the lines JL, LM, MN, NK′, and K′B (except for point B, point W, and point J);
- in a case of 18.2<a≤26.7,
- within a range of a figure surrounded by lines JL, LM, MN, NK′, K′B, BW, and WJ connecting each of seven points:
- point J (100−a−y, −0.0246a2+0.4476a+49.816, 0.0);
- point L (0.0197a2−1.5187a+64.723, 95.0−a−x, 5.0);
- point M (0.0145a2−1.3925a+66.539, 0.01a2−0.5903a+31.23, 100−a−x−y);
- point N (0.0213a2−1.8283a+67.31, −0.2706a+17.025, 100−a−x−y);
- point K′ (0.0196a2−1.7863a+58.515, 100−a−x−z, −0.0117a2+0.8999a+32.783);
- point B (0.0, 0.009a2−1.6045a+59.318, 100−a−y);
- and
- point W (0.0, 100−a, 0.0),
- or on the lines JL, LM, MN, NK′, and K′B (except for point B, point W, and point J);
- and
- in a case of 26.7<a≤36.7,
- within a range of a figure surrounded by lines JL, LM, MN, NK′, K′A, AB, BW, and WJ connecting each of eight points:
- point J (100−a−y, −0.0183a2+0.1399a+53.507, 0.0);
- point L (0.0081a2−0.9541a+57.893, 95.0−a−x, 5.0);
- point M (0.005a2−0.8563a+59.007, 0.03558a2−2.4139a+61.708, 100−a−x− y);
- point N (0.0108a2−1.1054a+55.507, 0.005a2−0.3563a+15.757, 100−a−x−y);
- point K′ (−0.0051a2+0.0929a+25.95, 0.0, 100−a−x);
- point A (0.0103a2−1.9225a+68.793, 0.0, 100−a−x);
- point B (0.0, 0.0046a2−1.41a+57.286, 100−a−y);
- and
- point W (0.0, 100−a, 0.0),
- or on the lines JL, LM, MN, NK′, K′A, and AB (except for point K′, point A, point B, point W, and point J).
Dependencies are inferred from the claim text.