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US 12,437,955 B2Granted
Method of forming field emission cathodes by co-electrodeposition
AssigneeNCX Corporation
InventorCheng Qian
Life of this patent
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Abstract
A method for fabricating an electron field emission cathode, the field emission cathode including a substrate having a field emission layer engaged therewith, where the field emission layer incorporates modified carbon nanotubes and a matrix material to improve field emission characteristics of the cathode and field emission cathode devices implementing such cathodes.
Claims24
A method of forming a field emission cathode, comprising:
- forming a field emission material, comprising:
- mixing a plurality of carbon nanotubes and a poly (3,4-ethylendioxythiophene)-poly (styrene sulfonic acid) (PEDOT:
- PSS) solution in water at a ratio to form a base mixture;
- exposing the base mixture to an ultrasonic dispersion process at a power of greater than 1 W/cm2 and at a frequency of about 20-50 kHz;
- introducing at least one matrix particle, at least one metal salt, at least one charger, or a combination thereof to the base mixture to form a field emission material precursor, the at least one metal salt being different from the at least one charger;
- and
- exposing the field emission material precursor to an ultrasonic dispersion process at a power of less than 1 W/cm2 and at a frequency of greater than 50 kHz to form the field emission material comprising a stable suspension of the field emission material precursor;
- depositing a layer of the field emission material on to at least a portion of a substrate via a co-electrodeposition process;
- drying the layer and the substrate at a temperature of about 20° C. to about 150° C. at atmosphere or under a vacuum;
- annealing the layer and the substrate at a temperature of about 300° C. to about 1000° C. under a vacuum;
- and
- activating the layer of the field emission material to obtain the field emission cathode.
9 more elements
A method of forming a field emission material, comprising:
- introducing a plurality of carbon nanotubes into a liquid medium;
- introducing a PEDOT:
- PSS solution into the liquid medium at a ratio to the plurality of carbon nanotubes;
- mixing the plurality of carbon nanotubes and the PEDOT:
- PSS solution via an ultrasonic dispersion process at a power of greater than 1W/cm2 and at a frequency of about 20-50 kHz to form a base mixture;
- introducing at least one matrix particle, at least one metal salt, at least one charger, or a combination thereof in the base mixture, the at least one metal salt being different from the at least one charger;
- and
- exposing the base mixture comprising the at least one matrix particle, the at least one metal salt, and the at least one charger to an ultrasonic dispersion process at a power of less than 1 W/cm2 and at a frequency of greater than 50 kHz to form the field emission material comprising a stable suspension of a field emission material precursor.
5 more elements
Dependencies are inferred from the claim text.