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US 12,435,275 B2Granted
Aromatic amide dispersant
AssigneeLubrizol Advanced Materials, Inc.
InventorsAndrew J. Shooter, Conor Wilkinson, Shabana Rafiq
Life of this patent
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Abstract
The present invention relates to a polymeric aromatic amide dispersant, and a composition containing a particulate solid, an aqueous or polar organic medium, and a polymeric aromatic amide dispersant having at least one tertiary amide linking group connecting through a carbonyl group of the amide to an aromatic ring having a residual carboxylic acidic group thereon. The invention further provides compositions for millbases, dispersions, coatings and inks.
Claims17
A dispersant or its salts comprising a polymer having the following structure, or salts thereof:
- n is 1, and m is equal to n in each polymer;
- R1 is independently CN, NO2, Cl, Br, CH3, NH2 or OH where a is 0 to 4;
- R2 is H, a C1-50 optionally substituted hydrocarbyl, or a C1-50 optionally substituted hydrocarbonyl group;
- G is a C1-50 hydrocarbyl group optionally substituted with heteroatoms represented as ether, ester, aldehyde, ketone, amide, urethane, alcohol or carboxylic acid groups, or a residue of an optionally substituted alkyl (meth)acrylate or (meth)acrylamide, or a ring opening product of an epoxide of the formula
- wherein R6 can individually on each occurrence be H or CH3 or C2H5 or one of the following groups:
- wherein D is C1-5 alkyl group, CN, OH, NO2, NH2, halogen, CO2H, SO3H, CH3 or OCH3;
- p is from 0 to 4;
- R3 is a linear or branched C1-50;
- T is —C(O)—CH(R4)CH2 or C1-5 hydrocarbyl chain;
- when G is C1-50 hydrocarbyl, T is —C(O)—CH(R4)CH2;
- when G is a residue of an optionally substituted alkyl (meth)acrylate or (meth)acrylamide, or a ring opening product of an epoxide, T is C1-5 hydrocarbyl chain;
- R4 is H or Me;
- Y independently in each repeat unit is C2-4 alkyleneoxy;
- Q comprises a naphthalene, a biphenyl, or a phenyl, wherein the carboxylic acid group attached to Q is attached to a carbon atom of the aromatic ring of Q;
- wherein the hydrogen of any acid in Formula I is optionally replaced by a metal, amine, or ammonium cation to place the dispersant in the form of a salt;
- and
- x is 2 to 90.
14 more elements
Dependencies are inferred from the claim text.