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US 12,428,512 B2Granted
Degradable crosslinkers for (meth)acrylic resins and methods thereof
Assignee3M Innovative Properties Company
InventorsAmanda K. Leone, Wayne S. Mahoney
Life of this patent
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Abstract
Disclosed herein is a thioester-containing (meth)acrylate compound comprising at least two thioester moieties and at least 2 (meth)acrylate moieties and a method for making such compounds. These compounds can be used in (meth)acrylic resins as a crosslinking agent. Upon exposure to a nucleophilic solvent, cured (meth)acrylic resins derived from these thioester-containing (meth)acrylate compounds can be degraded.
Claims9
A curable composition comprising:
- a mono (meth)acrylate ester monomer comprising at least 4 and no more than 20 carbon atoms;
- a thioester-containing (meth)acrylate crosslinking agent;
- and
- an initiator system,
- wherein the thioester-containing (meth)acrylic crosslinking agent is
- (a) of formula (I)
- wherein:
- R1 is (i) X2L2X2, wherein each X2 is independently S or O;
- and L2 is a divalent alkylenyl group, which may be linear or branched or
- (ii) C(X3)mL3C(X4)p, wherein X3 and X4 are independently a linear or branched alkyl group, L3 is divalent group comprising a S or O atom, m and p are independently selected from 0, 1 or 2, and n in formula (I) is an integer from 2 to 6, wherein p+m+n=6;
- R2 is a divalent alkylenyl group comprising at least 1 carbon atom and optionally comprising at least 1 ester linkage;
- R3 is a divalent alkylenyl group comprising at least 1 carbon atom and optionally comprising at least 1 ester linkage;
- and
- R4 is a H or a methyl group;
- (b) is at least one of the following:
- where R4 is H or methyl group.
13 more elements
Dependencies are inferred from the claim text.