Sliding band capacitor inductive coupling in a low temperature nuclear magnetic resonance probe and methods of use

A NMR probe (Nuclear Magnetic Resonance probe) adapted to detect a resonance of at least a nucleus from a sample, comprising:

• (i) a parent coil circuit comprising a parent coil, where the parent coil comprises a tapered inner conductance skirt;
• (ii) a cell adapted for holding the sample;
• and
• (iii) a sliding band capacitor adapted to adjust a frequency of the parent coil, where the sliding band capacitor comprises a sapphire insulator with a first volume magnetic susceptibility, at least one paramagnetic metal with a second volume magnetic susceptibility and at least one diamagnetic metal with a third volume magnetic susceptibility, where a sum of the first volume magnetic susceptibility and the second volume magnetic susceptibility and the third volume magnetic susceptibility is approximately zero, where the at least one paramagnetic metal is shaped in a form of a paramagnetic metal ring, where the paramagnetic metal ring is enclosed or surrounded by the at least one diamagnetic metal, where the paramagnetic metal ring comprises a titanium composition by volume between:
• a second lower limit of greater than approximately eighty (80) percent;
• and
• a second upper limit of greater than approximately ninety-eight (98) percent, where the sliding band capacitor is at a temperature, where the temperature of the sliding band capacitor is approximately 300° K when the NMR probe is introduced into a NMR instrument, where the temperature of the sliding band capacitor prior to detection of the resonance is reduced to between:
• a first lower limit of approximately 15 K;
• a first upper limit of approximately 80 K, where the NMR probe is adapted to introduce the sample into a magnetic field of the NMR instrument, where the sliding band capacitor is adapted to physically move relative to the tapered inner conductance skirt to adjust a capacitance of the sliding band capacitor to allow the parent coil to detect the resonance of at least the nucleus from the sample.

A method of detecting a resonance of at least a nucleus from a sample using a cooled NMR probe (Nuclear Magnetic Resonance probe), comprising:

• (i) selecting a parent coil circuit comprising a parent coil, where the parent coil comprises a tapered inner conductance skirt;
• (ii) selecting the sample;
• (iii) loading the sample into the NMR probe;
• (iv) introducing the NMR probe into a magnetic field of a NMR instrument, where the parent coil circuit is in electrical contact with the tapered inner conductance skirt, where a sliding band capacitor comprises a diamagnetic insulator with a first volume magnetic susceptibility, at least one paramagnetic metal with a second volume magnetic susceptibility and at least one diamagnetic metal with a third volume magnetic susceptibility, where a sum of the first volume magnetic susceptibility and the second volume magnetic susceptibility and the third volume magnetic susceptibility is approximately zero, where the at least one paramagnetic metal is adapted to form a paramagnetic metal ring, where the paramagnetic metal ring comprises a titanium composition by volume between:
• a lower limit of greater than approximately eighty (80) percent;
• and
• an upper limit of greater than approximately ninety-eight (98) percent, where the paramagnetic metal ring is enclosed or surrounded by the at least one diamagnetic metal, where the sliding band capacitor is adapted to be cooled to a temperature;
• (v) spinning the sample;
• and
• (vi) exciting the sample with a Radio Frequency (RF) field at a Larmor frequency, where the NMR probe is adapted to introduce the sample into the magnetic field of the NMR instrument, where the sliding band capacitor is adapted to physically move relative to the tapered inner conductance skirt to adjust a capacitance of the sliding band capacitor to allow the parent coil to detect the resonance of at least the nucleus from the sample.