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US 12,421,457 B2Granted
Production of ethylene and propylene from pyrolysis plastic oil
AssigneeTotalenergies Onetech
InventorsBenjamin Biber, Christine Richardson, Delphine Minoux, Keith Nelson, Cindy Adam
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Abstract
The disclosure relates to the purification and treatment of oil produced from the liquefaction of waste polymer like for instance the pyrolysis of waste plastic via the polymerization of dienes prior to further treatments.
Claims20
A process for the purification of a liquified waste polymer comprising the following steps:
- a) providing a feedstream (1) containing liquified waste polymer, wherein said feedstream (1) contains at least 0.1 wt. % to at most 80 wt. % of dienes based on the total weight of said feedstream (1);
- c) performing a polymerization reaction on said feedstream (1) under polymerization conditions to obtain a first product stream (3) comprising an oligomeric product (33) wherein the polymerization is a cationic polymerization and the cationic polymerization is performed in the presence of an acidic catalyst, wherein the acidic catalyst is a Brönsted acid or a Lewis acid;
- d) optionally, performing a neutralization reaction by contacting said first product stream (3) with a basic compound (25) to obtain a neutralized product stream (4) and removing said basic compound from neutralized product stream (4) to obtain a second product stream (5);
- g) performing a separation to separate the oligomeric product (33) from the purified liquified waste polymer (34);
- and
- j) performing a steam cracking reaction of said purified liquified waste polymer (34) to produce olefins such as ethylene and propylene and aromatics.
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An installation (100) for carrying out a process for the purification of a liquified waste polymer, said installation characterized in that it comprises:
- a polymerization section (C);
- an optional neutralization section (D);
- a separation section;
- and
- a steam cracking section comprising a steam cracker (37)
- wherein the polymerization section (C), the separation section and the steam cracking section are fluidically connected in series, and wherein the neutralization section (D) when present is placed downstream the polymerization section and upstream the separation section.
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Dependencies are inferred from the claim text.