US 12,420,273 B2 · Ozone purification catalyst and preparation method and application thereof

Abstract

An ozone purification catalyst, and a preparation method therefor and an application thereof are provided. The catalyst coating uses macroporous, high specific surface and CeO2 and/or La2O3 modified Al2O3 as the carrier material, and Mn and/or Pd as the active component. The preparation method is to prepare the Al2O3-based material by a sol-gel method, and then to load the active components on the carrier material, and to dry, calcinate and solidify to obtain the ozone purification catalyst. The catalysts as prepared shows a fast and efficient purification of ozone. The complete conversion temperature covers a wide range of temperature. The catalyst has excellent texture performance, high specific surface area and large pore volume, which is beneficial to ozone purification when the car is running at high speed. The particle sizes and colors of the catalyst can be modified according to various requirements. According to the actual application, it can be coated on the radiator fins of automobile water tanks, and any place where coating is allowed in public areas such as urban bus stations, stop signs, kiosks, roadside guardrails, or exterior walls of buildings that is in contact with outdoor air.

Claims19

Dependent claims

A method of preparing an ozone purification catalyst, comprising the following steps:

preparing a CeO2 and La2O3 modified Al2O3 carrier by a sol-gel method:
mixing a soluble Ce salt solution and a soluble La salt solution with pseudo-boehmite, adjusting the pH with an acid to 3.5 to 4.5, wherein the CeO2 has a content of 15 to 20 wt % in the carrier, the La2O3 has a content of 2 to 3 wt % in the carrier, and the Al2O3 has a content of 77 to 83 wt % in the carrier;
then calcining at 500 to 600° C. in air for 2 to 5 hours, and then at 800° C. in air for 2 to 5 hours to obtain the modified Al2O3 carrier;
loading a soluble Pd salt solution and/or a soluble Mn salt solution on the modified Al2O3 carrier by an equal-volume impregnation method:
wherein the Pd salt solution provides a Pd content, based on the element, of 0.3 to 0.5 wt % of the total weight of the ozone purification catalyst;
the Mn salt solution provides a Mn content, based on the element, of 0 to 8 wt % of the total weight of the ozone purification catalyst;
then, drying at 60 to 120° C. for 2 to 6 hours, and then calcining at 400 to 550° C. in air for 2 to 7 hours to obtain the ozone purification catalyst.

4 more elements

Dependencies are inferred from the claim text.

Ozone purification catalyst and preparation method and application thereof

Life of this patent

Ozone purification catalyst and preparation method and application thereof

Life of this patent

Abstract

Claims19