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US 12,415,963 B2Granted
Hydrogenation of acetylenes in a hydrocarbon stream
AssigneeKellogg Brown & Root LLC
InventorsDavid Sellinger, Robert Choi, Quo-Chen Yeh, Alok Srivastava, Kristine E. Hamilton, Michael A. Radzicki
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Abstract
A system for hydrogenation C3 and C4 acetylenes contained within a hydrocarbon stream generated in a stream cracker unit where a debutanizer is placed upstream of a depropanizer for more economical processing of the hydrocarbon stream to produce lighter hydrocarbons, where the system requires only one stripper tower downstream of hydrogenation to remove residual hydrogen.
Claims4
A process for selective hydrogenation of acetylenes comprising:
- directing a C3-C10 hydrocarbon stream to a debutanizer;
- condensing a debutanizer C3-C4 overhead stream;
- selectively hydrogenating C4 acetylenes in the condensed C3-C4 overhead stream in a C4 acetylene hydrogenation reactor to give a reactor outlet stream;
- directing the reactor outlet stream to a depropanizer downstream from the debutanizer;
- drawing a top stream from the depropanizer containing a C3 mixture comprising methyl acetylene and propadiene;
- drawing a bottom stream from the depropanizer containing a crude C4 mixture;
- directing the C3 mixture to a methyl acetylene and propadiene (MAPD) reactor and selectively hydrogenating the methyl acetylene and propadiene to give a crude propylene stream;
- and
- directing the crude propylene stream to a stripper column to vent off residual unreacted hydrogen.
6 more elements
Dependencies are inferred from the claim text.