Conductive polymer composition, substrate, and method for producing substrate

A conductive polymer composition comprising:

• a composite comprising
• a π-conjugated polymer (A), wherein the component (A) is a material in which at least one precursor monomer selected from the group consisting of pyrrole, thiophene, selenophene, tellurophene, aniline, polycyclic aromatic compounds, and derivatives thereof is polymerized, and
• a polymer (B) shown by the following general formula (1);
• H2O (D) for dispersing the composite;
• a water-soluble organic solvent (C);
• and
• a compound (E) shown by the following general formula (2),
• wherein an electric conductivity of a film with a thickness of 20 to 200 nm formed from the conductive polymer composition is less than 1.00E-05 S/cm, wherein the conductive polymer composition has a surface tension in a range of 20 to 50 mN/m,
• wherein R1 represents a hydrogen atom or a methyl group;
• Z represents any of a phenylene group, a naphthylene group, an ester group, an ether group, an amino group, and an amide group;
• when Z is a phenylene group or a naphthylene group, R2 represents any of a single bond and a linear, branched, or cyclic hydrocarbon group having 1 to 12 carbon atoms optionally having one or both of an ester group and an ether group;
• when Z is an ester group, an ether group, an amino group, or an amide group, R2 represents any of a single bond and a linear, branched, or cyclic hydrocarbon group having 1 to 14 carbon atoms optionally having an ether group;
• “m” represents any one of 1 to 3;
• R3, R5, and R7 each independently represent a hydrogen atom or a methyl group;
• R4 and R6 each independently represent any of a single bond and a linear, branched, or cyclic hydrocarbon group having 1 to 12 carbon atoms optionally having one or both of an ether group and an ester group;
• R8 represents any of a single bond, a methylene group, an ethylidene group, an isopropylidene group, an ether group, an ester group, an amino group, an amide group, and a linear, branched, or cyclic hydrocarbon group having 1 to 12 carbon atoms optionally containing an ether group, an ester group, an amino group, an amide group, or a heteroatom, and the amino groups and the amide groups each optionally contain any of a hydrogen atom and a linear, branched, or cyclic hydrocarbon group having 1 to 12 carbon atoms optionally containing a heteroatom;
• X1 and X2 each independently represent any of a single bond, a phenylene group, a naphthylene group, an ether group, an ester group, and an amide group;
• X3 represents any of a single bond, an ether group, and an ester group;
• Rf1 represents a fluorine atom or a trifluoromethyl group;
• “a”, b1, b2, and b3 satisfy 0.4≤a≤0.6, 0≤b1≤0.6, 0≤b2≤0.6, 0≤b3≤0.6, and 0<b1+b2+b3≤0.6;
• and “n” represents an integer of 1 to 4, and
• wherein R201 and R202 each independently represent any of a hydrogen atom, a heteroatom, and a linear, branched, or cyclic monovalent hydrocarbon group having 1 to 20 carbon atoms optionally having a heteroatom;
• R203 and R204 each independently represent any of a hydrogen atom and a linear, branched, or cyclic monovalent hydrocarbon group having 1 to 20 carbon atoms optionally having a heteroatom;
• R201, R203, or R201 and R204, are optionally bonded to each other to form a ring;
• L represents a linear, branched or cyclic tetravalent organic group having 1 to 20 carbon atoms optionally having a heteroatom;
• and when L has a heteroatom, the heteroatom is optionally an ion.