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US 12,415,724 B2Granted
Method for the preparation of synthesis gas
AssigneeTopsoe A/S
InventorsEmil Andreas Tjärnehov, Pat A. Han
Life of this patent
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Abstract
Method for the preparation of synthesis gas combining electrolysis of water, tubular steam reforming and autothermal reforming of a hydrocarbon feed stock in parallel.
Claims7
Method for the preparation of synthesis gas comprising the steps of:
- (a) providing a hydrocarbon feed stock;
- (b) preparing a separate hydrogen containing stream and a separate oxygen containing stream by electrolysis of water and/or steam;
- (c) steam reforming a first part of the hydrocarbon feed stock from step (a) in a tubular steam reformer to a tubular steam reformed gas comprising hydrogen, carbon monoxide and carbon dioxide, including recovering carbon dioxide in flue gas from burners in the tubular steam reformer and adding the recovered carbon dioxide to the steam reforming process;
- (d) autothermal reforming a second part of the hydrocarbon feed stock in an autothermal reformer with at least part of the oxygen containing stream obtained in step (b) to an autothermal reformed gas stream comprising hydrogen, carbon monoxide and carbon dioxide;
- (e) combining the steam reformed gas from step (c) with the autothermal reformed gas from step (d);
- (f) adding at least part of the separate hydrogen containing stream from step (b) into the hydrocarbon feed stock from step (a) and/or into the steam reformed gas stream from step (c) and/or into the autothermal reformed gas stream from step (d) and/or into the combined steam reformed gas and autothermal reformed gas stream from step (e);
- and
- (g) withdrawing the synthesis gas.
5 more elements
Dependencies are inferred from the claim text.