Hydrogen production from gasification of sour gas

A system comprising:

• a sour gas stream comprising hydrogen sulfide and at least one hydrocarbon, the sour gas stream having a molar flow rate of carbon (C) and a molar flow rate of hydrogen (H);
• an oxidizing stream comprising oxygen gas and having a molar flow rate of oxygen gas (O2) in a range of from 10% to 70% of C+H/4;
• a combustion reactor configured to receive the sour gas stream and the oxidizing stream, the combustion reactor configured to combust the sour gas stream to produce soot and sour syngas, wherein sub-stoichiometric combustion of the sour gas stream within the combustion reactor converts at least 10% of the carbon in the sour gas stream into soot;
• a mechanical separator configured to separate the soot from the sour syngas to produce a sour syngas stream comprising carbon dioxide, carbon monoxide, hydrogen, and hydrogen sulfide;
• a Claus unit configured to receive the sour syngas stream and a sulfur dioxide stream comprising sulfur dioxide, the Claus unit configured to react at least a portion of the hydrogen sulfide of the sour syngas stream with the sulfur dioxide of the sulfur dioxide stream to produce elemental sulfur and water, the Claus unit configured to discharge a sulfur stream comprising the elemental sulfur, the Claus unit configured to discharge a syngas stream comprising the carbon dioxide, the carbon monoxide, the hydrogen, the water, elemental sulfur vapor, a residual portion of the hydrogen sulfide, and a residual portion of the sulfur dioxide;
• a sour shift/hydrogenation reactor configured to receive the syngas stream and stean, the sour shift/hydrogenation reactor comprising a water-gas shift hydrogenation catalyst, the water-gas shift hydrogenation catalyst configured to convert at least a portion of the carbon monoxide of the syngas stream and steam to carbon dioxide and hydrogen to produce a shifted sour gas stream, the water-gas shift hydrogenation catalyst configured to reduce the elemental sulfur vapor and the residual portion of the sulfur dioxide into hydrogen sulfide, the shifted sour gas stream substantially free of elemental sulfur and sulfur dioxide;
• a quench tower configured to receive the shifted sour gas stream and separate water from the shifted sour gas stream to produce a dehydrated sour gas stream;
• an amine unit configured to receive the dehydrated sour gas stream, the amine unit configured to contact the dehydrated sour gas stream with a lean amine solvent to extract the residual portion of the hydrogen sulfide from the dehydrated sour gas stream into the lean amine solvent to produce a sweet gas stream and a rich amine solvent, the sweet gas stream comprising the carbon dioxide and the hydrogen, the amine unit configured to boil off the residual portion of the hydrogen sulfide from the rich amine solvent to produce an acid gas stream and regenerate the lean amine solvent, the acid gas stream comprising the residual portion of the hydrogen sulfide;
• and
• a purifier configured to receive the sweet gas stream and separate hydrogen from the sweet gas stream to produce a hydrogen product stream and an exhaust stream, the hydrogen product stream comprising a majority of the hydrogen from the sweet gas stream, the exhaust stream comprising a remainder of the sweet gas stream, wherein the combustion reactor is configured to receive at least a portion of the exhaust stream.