Polymer and organic electronic device using same
AssigneeIndustry-Academic Cooperation Foundation Gyeongsang National University
InventorsSoon-Ki Kwon, Yun-Hi Kim, Cheng Sun
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Abstract
The present invention relates to a novel polymer and an organic electronic device using same. In the polymer according to the present invention, a cyclic electron-donor, including thiophene, selenophene, or a combination thereof, is introduced into a central skeleton having an A-D-A structure including an electron-donor and electron-acceptor unit. Thus, the polymer has not only excellent chemical and thermal stability, but also good crystallinity. Moreover, intermolecular stacking is possible, and thus charge mobility can be maximized.
Claims13
A polymer comprising:
- a repeating unit represented by the following Chemical Formula 1 and a repeating unit represented by Chemical Formula 2:
- wherein
- R1 to R4 are independently of one another C1-C30 alkyl;
- X1 to X4 are independently of one another O, S, or Se;
- V1 and V2 are independently of each other a fused ring having methylidene as a linking group, the fused ring may be independently of each other further substituted by one or more substituents selected from C1-C30 alkyl, C1-C30 alkoxy, C1-C30 alkylthio, halogen, cyano, haloC1-C30 alkyl, nitro, and hydroxy, —CH2— of the fused ring may be replaced with carbonyl, thiocarbonyl, or
- in which R is independently of each other hydrogen, C1-C30 alkyl, C1-C30 alkoxy, C1-C30 alkylthio, halogen, cyano, nitro, hydroxy, haloC1-C30 alkyl, C1-C30 alkylcarbonyl, or C1-C30 alkylcarbonyloxy, and the fused ring may include one or more heteroatoms selected from N, O, S, and Se;
- and
- Ar is benzodithiophenylene, benzodithienothiophenylene, naphthodithiophenylene, thiophenylene, benzothienoselenophenylene, benzodiselenophenylene, benzodiselenoselenophenylene, naphthodiselenophenylene, selenophenylene, or a combination thereof, and Ar may be independently of each other further substituted by one or more substituents selected from C1-C30 alkyl, C1-C30 alkoxy, C1-C30 alkylthio, C6-C30 aryl, C3-C30 heteroaryl, halogen, cyano, nitro, hydroxy, and a combination thereof.
Dependencies are inferred from the claim text.