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US 12,410,263 B2Granted
Modified high-Cis polybutadiene polymer, related methods and rubber compositions
AssigneeBridgestone Americas Tire Operations, LLC
InventorsJeffrey A. Cicerchi, Terrence E. Hogan, James J. Kuhel, Jr.
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Abstract
Disclosed herein are a process for preparing a modified high-cis polybutadiene polymer, a modified high-cis polybutadiene polymer, and tire components made using the modified high-cis polybutadiene polymer. The processes make use of a functionalizing compound of formula (I) to prepare the modified high-cis polybutadiene from a quantity of 1,3-butadiene monomer using a specified catalyst system.
Claims17
A modified high-cis polybutadiene polymer having
- polymer chains bonded to a residue of a functionalizing compound having formula (I) as follows
- where X is a group reactive with the living end polymer chains and is selected from the group consisting of cyano, epoxy, ketone, aldehyde, ester, and acid anhydrides,
- R1 is selected from hydrocarbylene of C1-C20, wherein each of the foregoing optionally contain one unsaturated carbon-carbon bond,
- each R′ is selected from alkoxy of C1-C20, and
- R″ is selected from alkyl of C1-C20 or aryl of C6-C20,
- wherein each polymer chain is bonded to the residue of the functionalizing compound through the X group, and the modified high-cis polybutadiene polymer has
- a cis 1,4-bond content of 92-98%,
- an initial Mooney viscosity ML1+4 at 100° C. of 20-100, and
- an aged Mooney viscosity ML1+4 at 100° C. of no more than 120, wherein the aged Mooney viscosity is determined after aging at 100° C. for 2 days.
6 more elements
Dependencies are inferred from the claim text.