Anisotropic rare earth sintered magnet and method for producing the same

Abstract

Provided are an anisotropic rare earth sintered magnet having a ThMn12-type crystal compound as a main phase and exhibits good magnetic characteristics, and a method for producing it. The anisotropic rare earth sintered magnet has a composition of a formula (R1-aZra)v(Fe1-bCob)100-v-w-x-y(M11-cM2c)wOxCy (where R is one or more kinds selected from rare earth elements and indispensably includes Sm, M1 is one or more kinds of elements selected from the group consisting of V, Cr, Mn, Ni, Cu, Zn, Ga, Al, and Si, M2 is one or more kinds of elements selected from the group consisting of Ti, Nb, Mo, Hf, Ta, and W, and v, w, x, y, a, b, and c each satisfy 7≤v≤15 at %, 4≤w≤20 at %, 0.2≤x≤4 at %, 0.2≤y≤2 at %, 0≤a≤0.2, 0≤b≤0.5, and 0≤c≤0.9), which contains a main phase of a ThMn12-type crystal compound in an amount of 80% by volume or more with the average crystal particle diameter of the main phase being 1 μm or more, which contains an R oxycarbide in the grain boundary area, and which has a density of 7.3 g/cm3 or more. The production method for the anisotropic rare earth sintered magnet includes grinding an alloy that contains a ThMn12-type crystal compound phase but does not contain an oxycarbide, then molding it in a mode of pressure powder molding with magnetic field application thereto to give a molded article, and thereafter sintering it at a temperature of 800° C. or higher and 1400° C. or lower to form an oxycarbide in the grain boundary area.

Dependencies are inferred from the claim text.