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US 12,404,459 B2Granted
Process for the recycling and cracking waste plastics based oil
AssigneeTotalenergies Onetech
InventorsBenjamin Biber, Christine Richardson, Delphine Minoux, Keith Nelson, Cindy Adam
Life of this patent
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Abstract
The disclosure relates to the purification and treatment of oil produced from the liquefaction of waste polymer like for instance the pyrolysis of waste plastic via the polymerization of dienes prior to further treatments.
Claims19
Process for a purification of liquified waste polymer comprising the following steps:
- a) providing a feedstream (1) containing liquified waste polymer, wherein said feedstream (1) contains at least 0.1 wt. % to at most 80 wt. % of dienes based on the total weight of said feedstream (1);
- c) performing a polymerization reaction on said feedstream (1) under polymerization conditions to obtain a first product stream (3) comprising an oligomeric product (33) wherein the cationic polymerization is performed in the presence of an acidic catalyst;
- d) optionally, performing a neutralization reaction by contacting said first product stream (3) with a basic compound (25) to obtain a neutralized product stream (4) and removing said basic compound from neutralized product stream (4) to obtain a second product stream (5);
- g) performing a separation to separate the oligomeric product (33) from the purified liquified waste polymer (34);
- and
- k) performing a cracking reaction wherein said purified liquified waste polymer (34) is cracked on a catalyst being a 10 MR or 12 MR molecular sieve at a temperature ranging from 450° C. to 650° C., a total pressure ranging from 0.5 to 10 barg and/or with an hydrogen partial pressure ranging from 0 to 7.5 barg to crack the olefins and/or paraffins of said purified liquified waste polymer into olefins having 2 to 4 carbon atoms.
3 more elements
Dependencies are inferred from the claim text.