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US 12,404,173 B2Granted
Solid electrolyte, and method for producing same
AssigneeLG Energy Solution, Ltd.
InventorsVin-Na Jo, Hyea-Eun Han, Je-Yne Lyoo, Seung-Tae Hong
Life of this patent
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Abstract
The present disclosure relates to a novel material used as a solid electrolyte for an all-solid-state battery. Particularly, the present disclosure relates to a sulfide-based solid electrolyte including lithium, sulfur, phosphorus and zinc elements, and a method for preparing the same.
Claims13
A sulfide-based solid electrolyte comprising a compound represented by the following Chemical Formula 1 or Chemical Formula 2:
- LixZnyPzS6 [Chemical Formula 1]
- wherein 1≤x≤4, 0<y≤2, and 0<z≤3;
- Li2+2kZn1−kP2S6 [Chemical Formula 2]
- wherein 0≤k<1;
- wherein the compound has a crystal structure satisfying the following conditions (a)-(c):
- (a) a space group that belongs to P31m (No. 162);
- (b) unit cell parameters of a=6.03±0.5 Å and c=6.59±0.5 Å;
- and
- (c) crystallographic coordinates of cations occupying 2c, 2d and 2e coordinates in a unit cell with a site occupancy of each coordinate of larger than 0 and equal to or less than 1, and a crystallographic coordinate of anions occupying 6k coordinate in a unit cell with a site occupancy of 6k of larger than 0 and equal to or less than 1, wherein each of the coordinates represents the following:
- 2c (⅓, ⅔, 0);
- 2d (⅓, ⅔, ½);
- 2e (0, 0, z), wherein 0.30≤z≤0.33;
- and
- 6k (x, 0, z), wherein 0.325≤x≤0.35 and 0.23≤z≤0.28.
11 more elements
Dependencies are inferred from the claim text.