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US 12,398,230 B2Granted
Curing resin composition, curing method therefor, and molded article
AssigneeMitsubishi Gas Chemical Company, Inc.
InventorsNoriyoshi Ogawa, Shun Ishikawa
Life of this patent
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Abstract
Provided is a curable resin composition which can be molded by casting to obtain composite materials each composed of a polycarbonate resin and an acrylic resin and having high transparency and high impact strength. More specifically, provided is a curing resin composition comprising an acrylic monomer having a saturated group, a polycarbonate resin having an unsaturated-group-containing terminal structure at a molecular end, and a free-radical polymerization initiator.
Claims14
A curable resin composition comprising:
- an acrylic monomer having a saturated group;
- a polycarbonate resin containing Structural unit (2) below which has a terminal structure represented by Structural formula (1) below with an unsaturated group attached to the end of the molecule;
- and
- a radical polymerization initiator:
- (in Formula (1),
- A represents a vinyl group, an isopropenyl group, a styryl group or a methine group,
- R1-R2 each independently represent a single bond or an optionally substituted C1-C20 alkylene group,
- R3-R4 each independently represent hydrogen, or an optionally substituted C1-C20 alkyl group, C1-C10 alkoxy group, C6-C12 aryl group or benzotriazole group,
- Z represents an ether group, a carbonyl group, an ester group or a single bond,
- a is an integer of 1-3, and
- Y represents an ether bond or an ester group);
- and
- (in Formula (2),
- R5-R8 each independently represent hydrogen, or an optionally substituted C1-C20 alkyl group, C6-C12 aryl group, C1-C5 alkoxy group or C7-C17 aralkyl group,
- b is an integer of 1 or greater,
- X is as follows:
- wherein,
- R9 and R10 each independently represent hydrogen, fluorine, chlorine, bromine or iodine, or an optionally substituted C1-C20 alkyl group, C1-C5 alkoxy group or C6-C12 aryl group, or R9 and R10 bind to each other and represent a group forming a C5-C20 carbocyclic ring or a heterocyclic ring having 5-12 elements,
- R11 and R12 each independently represent hydrogen, fluorine, chlorine, bromine or iodine, or an optionally substituted C1-C9 alkyl group, C1-C5 alkoxy group or C6-C12 aryl group,
- R13 is an optionally substituted C1-C9 alkylene group,
- c represents an integer of 0-20, and
- d represents an integer of 1-500,
- provided that the composition further comprises a second polycarbonate resin if R5-R8 are hydrogen and R9 and R10 are methyl groups),
- wherein the concentration of the acrylic monomer contained in the curable resin composition is in a range of 95-70 mass %, relative to the whole curable resin composition.
21 more elements
Dependencies are inferred from the claim text.