Fluorine-containing polymer, mold release agent composition and mold release method
AssigneeDaikin Industries, Ltd.
InventorsHidekazu Uehata, Yasushi Nakamae
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Abstract
Provided is a mold release agent composition which has excellent mold releasability and excellent dissolution stability (storage stability). A mold release agent composition that contains: (1) a fluorine-containing polymer which has repeating units derived from (a) a fluorine-containing monomer having a perfluoroalkyl group, (b) a non-fluorine monomer having a hydrocarbon group and (c) a non-fluorine monomer having a phosphoric acid group, and wherein the amount of the phosphoric acid group-containing non-fluorine monomer (c) is 8% by weight or less relative to the fluorine-containing polymer; and (2) at least one liquid medium which is selected from among water and organic solvents.
Claims18
A fluorine-containing polymer having repeating units derived from:
- (a) a fluorine-containing monomer having a perfluoroalkyl group,
- (b) a fluorine-free monomer having a hydrocarbon group, and
- (c) a fluorine-free monomer having a phosphate group,
- wherein
- the fluorine-containing monomer (a) is a compound represented by formula:
- CH2═C(—X11)—C(═O)—Y11—Y12—Rf,
- wherein
- X11 is a hydrogen atom, or a methyl group,
- Y11 is —O— or —NH—,
- Y12 is a direct bond, a divalent aliphatic hydrocarbon group, a divalent aromatic hydrocarbon group, or a divalent cycloaliphatic hydrocarbon group, and
- Rf is a perfluoroalkyl group having 6 to 20 carbon atoms,
- wherein the hydrocarbon group in the hydrocarbon group-containing fluorine-free monomer (b) has 1 to 40 carbon atoms,
- wherein an amount of the fluorine-containing monomer (a) is 35 to 80% by weight, based on the fluorine-containing polymer,
- wherein an amount of the hydrocarbon group-containing fluorine-free monomer (b) is 15 to 50% by weight, based on the fluorine-containing polymer,
- wherein an amount of the phosphate group-containing fluorine-free monomer (c) is 0.1 to 4% by weight, based on the fluorine-containing polymer,
- wherein the fluorine-containing polymer does not comprise a repeating unit derived from a silicon-containing monomer, and
- wherein a chain transfer agent is not used in the production of the fluorine-containing polymer.
Dependencies are inferred from the claim text.