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US 12,391,792 B2Granted
Hardener formulation for cold curing epoxy systems
AssigneeBlue Cube IP LLC
InventorMarkus Schroetz
Life of this patent
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Abstract
Provided herein is a hardener composition comprising (a) a first adduct comprising a reaction product of a liquid epoxy resin and isophorone diamine; (b) a second adduct comprising a reaction product of a liquid epoxy resin and m-xylylenediamine; and (c) an accelerator component comprising methanesulfonic acid.
Claims13
A curable composition comprising:
- (a) at least one liquid epoxy resin selected from the group consisting of bisphenol A diglycidyl ether, bisphenol F diglycidyl ether, a novolac epoxy resin, and mixtures thereof;
- and
- (b) a hardener composition comprising:
- (1) from about 5 weight percent to about 50 weight percent, based on the total weight of the hardener composition, of a first epoxy-amine adduct,
- (2) from about 2 weight percent to about 30 weight percent, based on the total weight of the hardener composition, of a second epoxy-amine adduct, and
- (3) from about 1 weight percent to about 15 weight percent, based on the total weight of the hardener composition, of an accelerator component comprising methanesulfonic acid;
- wherein the first epoxy-amine adduct is provided as an epoxy-amine adduct composition comprising about 30% to about 90% by weight of an adduct of bisphenol A diglycidyl ether and isophorone diamine and about a weight balance of unreacted isophorone diamine;
- wherein the second epoxy-amine adduct is provided as an epoxy-amine adduct composition comprising about 30% to about 90% by weight of an adduct of bisphenol A diglycidyl ether and m-xylylenediamine and about a weight balance of unreacted m-xylylenediamine;
- and
- wherein a ratio of the epoxy-equivalent in (a) to the amine-hydrogen equivalent in (b) is from about 1:0.5 to about 1:1.5.
7 more elements
Dependencies are inferred from the claim text.